Determination of cyantraniliprole in green and red chilli fruits and Indian soil using LC-MS/MS and its dietary risk assessment

被引：0

作者：

Poornima, G. ^{[1
]}

Naik, R. Harischandra ^{[1
,2
,3
]}

Pallavi, M. S. ^{[1
,5
]}

Saraswati, M. ^{[1
]}

Ratnamma, P. ^{[1
]}

Shwetha, A. ^{[1
]}

Paramasivam, M. ^{[4
]}

Bheemanna, M. ^{[1
]}

Nidoni, R. Udaykunar ^{[1
]}

机构：

[1] Univ Agr Sci, Pesticide Residue & Food Qual Anal Lab, Raichur 584104, Karnataka, India

[2] Coll Hort, Bengaluru, India

[3] Univ Hort Sci, Bagalkot 587104, India

[4] Tamil Nadu Agr Univ, Coimbatore 641003, Tamil Nadu, India

[5] KSN Univ Agr & Hort Sci, Shivamogga 577412, India

来源：

JOURNAL OF FOOD COMPOSITION AND ANALYSIS | 2025年 / 141卷

关键词：

Chilli; Cyantraniliprole; Dissipation; LC-MS/MS; QuEChERS; Hazard index; MAJOR METABOLITE RESIDUES; DISSIPATION KINETICS; PESTICIDE-RESIDUES; ESI-MS/MS; INSECTICIDE; CHLORANTRANILIPROLE; VEGETABLES; PEPPER; LETHAL; J9Z38;

D O I：

10.1016/j.jfca.2025.107294

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Cyantraniliprole belongs to the diamide class insecticide and is a ryanodine receptor agonist. It is highly effective against the lepidoptera and has systemic activity against sucking pests. The quantitative estimation of cyantraniliprole in green chilli, red chilli and soil was standardized and validated using a liquid chromatographytandem mass spectrometer (LC-MS/MS). The correlation coefficient was greater than 0.999 for the solvent and matrix linearity. The limit of quantification was 2 mu g kg- 1 for all matrices. The method involves modified QuEChERS extraction with acetonitrile, and purification by dispersive solid phase extraction using primary secondary amine, magnesium sulfate and graphitized carbon black. Recoveries in green chilli, red chilli and soil were 95-115 %, 99-111 % and 83-98 %, respectively. The cyantraniliprole residues ranged from 210 to 410 mu g kg- 1 at 2 hours after application and dissipated to half of their concentration by 2.80-3.26 days for standard and double the standard dose (60 and 120 g a. i. ha- 1), respectively. At harvest residues in red chilli and soil were below the quantification limit. The dietary risk assessment showed that the hazard index was less than one in green chilli and was found to be safe for human consumption.

引用

页数：8

共 39 条

[1] Anastassiades M., Lehotay S.J., Stajnbaher D., Schenck F.J., Fast and easy multiresidue method employing acetonitrile extraction/ partitioning and “dispersive solid-phase extraction” for the determination of pesticide residues in produce, J. AOAC Int, 86, pp. 412-431, (2003)
[2] Cabras P., Spanedda L., Cabitza F., Cubeddu M., Martini M.G., Brandolini V., Pirimicarb and its metabolite residues in lettuce. Influence of cultural environment, J. Agric. Food Chem., 38, 3, pp. 879-882, (1990)
[3] Calderon R., Garcia-Hernandez J., Palma P., Leyva-Morales J.B., Zambrano-Soria M., Bastidas-Bastidas P.J., Godoy M., Assessment of pesticide residues in vegetables commonly consumed in Chile and Mexico: potential impacts for public health, J. Food Compo. Anal., 108, (2022)
[4] Chawan R., Harischandra Naik R., Pallavi M.S., Rachappa V., Pramesh D., Bheemanna M., LC-ESI-MS/MS method for determination of chlorantraniliprole residue and its dissipation kinetics in pigeonpea, Pest. Res J., 32, 1, pp. 96-106, (2020)
[5] CIBRC, Ministry of Agriculture and Farmer Welfare, 31st May 2018, Insectic. Agric. Use, pp. 2-52, (2018)
[6] Cordova D., Benner E., Sacher M., Rauh J., Sopa J., Lahm G., Anthranilic diamides: a new class of insecticides with a novel mode of action, ryanodine receptor activation, Pest. Biochem Physiol., 84, 3, pp. 196-214, (2006)
[7] Darko G., Akoto O., Dietary intake of organophosphorus pesticide residues through vegetables from Kumasi Ghana, Food Chem. Toxicol., 46, pp. 3703-3706, (2008)
[8] Dong F.S., Liu X.G., Xu J., Li J., Li Y.B., Shan W.L., Song W.C., Zheng Y.Q., Determination of cyantraniliprole and its major metabolite residues in vegetable and soil using ultra-performance liquid chromatography/tandem mass spectrometry, Biomed. Chromatogr., 26, pp. 377-383, (2012)
[9] Dong J.F., Wang K., Li Y., Wang S.L., Lethal and sublethal effects of cyantraniliprole on Helicoverpa assulta (Lepidoptera: Noctuidae), Pest. Biochem Physiol., 136, pp. 58-63, (2017)
[10] (2014)

← 1 2 3 4 →