Biomass-derived magnetic amorphous carbon as an efficient catalyst in the conversion of fructose into 5-hydroxymethylfurfural

被引:0
|
作者
Dang, Tuan Minh [1 ,2 ]
Nguyen, Trinh Hao [1 ,2 ]
Nguyen, Ha Khanh [1 ,2 ]
Phan, Ha Bich [1 ,2 ,3 ]
Nguyen, Hai Truong [1 ,2 ]
Tran, Phuong Hoang [1 ,2 ]
机构
[1] Univ Sci, Fac Chem, Dept Organ Chem, Ho Chi Minh City, Vietnam
[2] Vietnam Natl Univ, Ho Chi Minh City, Vietnam
[3] Inst Publ Hlth, Ho Chi Minh City, Vietnam
关键词
SOLID ACID CATALYST; SULFURIC-ACID; DEHYDRATION; HMF; CELLULOSE; 2,5-DIFORMYLFURAN; SOLVENT; LIGNIN;
D O I
10.1039/d4dt03566f
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Fructose dehydration yields 5-hydroxymethylfurfural (5-HMF), a multifaceted precursor for clean fuels, advanced biofuels, and fuel additives. In this work, we developed a magnetic solid acid (BMSA) derived from rice husk as a proficient catalyst in the production of 5-HMF. This study investigated the influence of calcination conditions on the acid content of the catalyst, with the objective of enhancing its performance. The study factors include the effects of temperature, solvent, reaction duration, and catalyst mass, which were investigated. 5-HMF was synthesized with a yield of 72% in 3 h using 2 mg of catalyst in DMSO at 120 degrees C. Interestingly, the catalyst exhibited facile recovery with an external magnet and demonstrated efficient reusability for up to four cycles.
引用
收藏
页码:4965 / 4976
页数:12
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