Iminodiacetic acid stabilized 3d-4f clusters: Synthesis, structure, and magnetism

被引：2

作者：

Qi, Ming-Qiang ^{[1
,2
]}

Zhang, Hong-Tai ^{[1
,2
]}

Diao, Xin-Ya ^{[1
,2
]}

Kong, Xiang-Jian ^{[1
,2
]}

Long, La-Sheng ^{[1
,2
]}

Zheng, Lan-Sun ^{[1
,2
]}

机构：

[1] Xiamen Univ, Coll Chem & Chem Engn, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China

[2] Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2025年 / 534卷

基金：

中国国家自然科学基金;

关键词：

Clusters; 3d-4f; Synthetic strategies; Crystal structure; MONTE-CARLO SIMULATIONS; HETEROMETALLIC CLUSTERS; QUANTUM; LN; MOLECULES; CHEMISTRY; DESIGN; IONS; CAGE;

D O I：

10.1016/j.ccr.2025.216585

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Clusters, composed of several to hundreds of metal atoms or ions encapsulated by organic ligands, occupy a unique intermediate state between molecules and bulk materials. With the rise of atomic precision manufacturing, clusters have garnered increasing attention for their diverse potential applications across various fields. Lanthanides (4f elements), essential for modern technology, possess a rich array of chemical properties and distinctive physicochemical characteristics due to their unique electronic configurations. Recent years have seen substantial progress in research on cluster systems incorporating 4f elements and first-row transition metals (3d elements), particularly in tailoring their structures and enhancing their performance. This review systematically summarizes the synthetic strategies, structural features, physicochemical properties, and potential applications of 3d-4f clusters based on iminodiacetic acid and its derivatives as ligands. Additionally, it highlights the challenges and future research directions in the field.

引用

页数：13

共 99 条

[51] Lantern-shaped 3d-4f high-nuclearity clusters with magnetocaloric effect [J].