Synthesis and Characterisation of Phosphino-Aryloxide Rare Earth Complexes

被引：0

作者：

Alexopoulos, Elias ^{[1
]}

Liu, Yu ^{[1
]}

Bowles, Alex W. J. ^{[1
]}

Reant, Benjamin L. L. ^{[2
]}

Ortu, Fabrizio ^{[1
]}

机构：

[1] Univ Leicester, Sch Chem, Univ Rd, Leicester LE1 7RH, England

[2] Univ Manchester, Dept Chem, Oxford Rd, Manchester M13 9PL, England

来源：

MOLECULES | 2024年 / 29卷 / 23期

关键词：

lanthanide; rare earth; coordination chemistry; crystallography; NMR; FRUSTRATED LEWIS PAIRS; 1,4-ADDITION REACTIONS; CARBON-DIOXIDE; ACTIVATION; REACTIVITY; POLYMERIZATION; REDUCTION; DIHYDROGEN; CO2; THF;

D O I：

10.3390/molecules29235757

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A series of homoleptic rare earth (RE) complexes bearing phosphino-aryloxide ligands (1-RE, 2-La) has been prepared. The complexes have been characterised using multinuclear NMR and IR spectroscopy, X-ray crystallography and elemental analysis. Structural characterisation highlighted the different RE-P interactions as a result of differing Lewis acidity and ionic size across the series, hinting at the possibility of FLP-type activity. The potential reactivity of these complexes has been tested by reacting them with small molecules (H2, CO, CO2). A series of side-products (3-RE) has also been observed, isolated and characterised, featuring the incorporation of a phosphonium-aryloxide ligand.

引用

页数：17

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