Carbon sequestration into lime-stabilized soils: Engineering and mineralogical characterization

Stabilizing weak clayey soils with lime is an effective method for improving the mechanical properties of soil. However, lime production is an energy-intensive process producing significant CO2 emissions in lime-stabilized soils, which can be counteracted through accelerated carbonation that enhances its engineering performance. The present study evaluates accelerated carbonation of lime-treated soils by adding gaseous (CO2-rich gas), liquid (water-CO2 mixture), and solid (sodium bicarbonate) CO2 sources. Results indicated that samples carbonated with gaseous CO2 exhibited 100% lime carbonation, while samples treated with solid and aqueous sources of CO2 had a mean lime carbonation of 60% and 40%, respectively. All lime-treated-carbonated samples exhibited a mean 50% increase in unconfined compressive strength compared to the untreated samples after a 7day curing period. Durability evaluation through cyclic wetting and drying indicated that the carbonated samples had higher durability than the untreated samples. X-ray computed tomography showed that adding solid and liquid sources of CO2 facilitated the flocculation of montmorillonite, reducing the porosity. However, a higher dosage of solid CO2 induced clay dispersion, increasing the porosity. X-ray diffraction and thermogravimetric analysis verified CO2 sequestration through the formation of calcite, a thermodynamically stable polymorph of calcium carbonate.