Nitrogen Doped Carbon Quantum Dots as Fluorescence "Turn-Off-On" Sensor for Detection of Fe3+ Ions and Ascorbic Acid in Moringa oleifera and Citrus Lemon

被引:4
作者
Sahu, Girish [1 ,2 ]
Chawre, Yogyata [1 ]
Kujur, Ankita Beena [1 ]
Miri, Pinki [2 ]
Sinha, Akash [1 ,2 ]
Nagwanshi, Rekha [3 ]
Karbhal, Indrapal [1 ]
Ghosh, Kallol K. [1 ]
Jena, Vinod K. [2 ]
Satnami, Manmohan L. [1 ]
机构
[1] Pt Ravishankar Shukla Univ, Sch Studies Chem, Raipur 492010, Chhattisgarh, India
[2] Govt Nagarjuna P G Coll Sci, Dept Chem, Raipur 492010, Chhattisgarh, India
[3] Govt P G Sci Coll, Dept Chem, Ujjain 456010, Madhya Pradesh, India
关键词
Carbon quantum dots; Quantum yield; Turn-off; Turn-on; Detection of Fe3+ ions and ascorbic acid; PROBE; BIOMASS; IRON; PHOTOLUMINESCENCE; SAMPLES; FACILE; LIQUID; SYSTEM;
D O I
10.1007/s10895-024-04012-0
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
In recent year, the uses of carbon quantum dots (CQDs) have increased in many fields. Herein we report, synthesis of fluorescent nitrogen doped carbon quantum dots (N-CQDs) by simple and ecofriendly hydrothermal method. The as-synthesized N-CQDs were characterized by various techniques and the quantum yield was also calculated. Then, application of N-CQDs were performed as a sensor for detection of ferric ions (Fe3+) based on static quenching mechanism (turn-off) which occurred due to formation of non-fluorescent complex between N-CQDs and Fe3+ ions. Interestingly, fluorescence intensity of quenched N-CQDs has been significantly recovered (turn-on) by addition of ascorbic acid (AA). The recovery mechanism is based on the redox reaction between Fe3+ ions and AA. Thus, N-CQDs has been used as fluorescence "turn-off-on" sensor for detection of Fe3+ ions and AA. Further this detection system is used for detecting Fe3+ ions in Moringa oleifera and AA in citrus lemon.
引用
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页数:13
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共 58 条
[1]   Iron homeostasis [J].
Andrews, Nancy C. ;
Schmidt, Paul J. .
ANNUAL REVIEW OF PHYSIOLOGY, 2007, 69 :69-85
[2]   Ascorbic acid: much more than just an antioxidant [J].
Arrigoni, O ;
De Tullio, MC .
BIOCHIMICA ET BIOPHYSICA ACTA-GENERAL SUBJECTS, 2002, 1569 (1-3) :1-9
[3]   Surface decoration of carbon nanosheets with amino-functionalized organosilica nanoparticles [J].
Baikousi, M. ;
Dimos, K. ;
Bourlinos, A. B. ;
Zboril, R. ;
Papadas, I. ;
Deligiannakis, Y. ;
Karakassides, M. A. .
APPLIED SURFACE SCIENCE, 2012, 258 (08) :3703-3709
[4]   Efficient Continuous Hydrothermal Flow Synthesis of Carbon Quantum Dots from a Targeted Biomass Precursor for On-Off Metal Ions Nanosensing [J].
Baragau, Ioan-Alexandru ;
Power, Nicholas P. ;
Morgan, David J. ;
Lobo, Richard A. ;
Roberts, Christopher S. ;
Titirici, Maria-Magdalena ;
Middelkoop, Vesna ;
Diaz, Adriana ;
Dunn, Steven ;
Kellici, Suela .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2021, 9 (06) :2559-2569
[5]  
Barrita JLS., 2013, Oxidative Stress Chronic Degener Dis Role Antioxid, V449, P52181
[6]   Multiple Effects of Ascorbic Acid against Chronic Diseases: Updated Evidence from Preclinical and Clinical Studies [J].
Berretta, Massimiliano ;
Quagliariello, Vincenzo ;
Maurea, Nicola ;
Di Francia, Raffaele ;
Sharifi, Saman ;
Facchini, Gaetano ;
Rinaldi, Luca ;
Piezzo, Michela ;
Manuela, Ceccarelli ;
Nunnari, Giuseppe ;
Montopoli, Monica .
ANTIOXIDANTS, 2020, 9 (12) :1-27
[7]   Hydroxyapatite supported N-doped carbon quantum dots for visible-light photocatalysis [J].
Chang, Q. ;
Li, K. K. ;
Hu, S. L. ;
Dong, Y. G. ;
Yang, J. L. .
MATERIALS LETTERS, 2016, 175 :44-47
[8]  
Dewangan L, 2021, ACS Appl. Nano Mater
[9]   N-doped, silver, and cerium co-doped carbon quantum dots based sensor for detection of Hg2+ and captopril [J].
Dewangan, Lakshita ;
Chawre, Yogyata ;
Korram, Jyoti ;
Karbhal, Indrapal ;
Nagwanshi, Rekha ;
Jain, Vishal ;
Satnami, Manmohan L. .
MICROCHEMICAL JOURNAL, 2022, 182
[10]   MPA-CdTe quantum dots as “on-off-on” sensitive fluorescence probe to detect ascorbic acid via redox reaction [J].
Ding M. ;
Wang K. ;
Fang M. ;
Zhu W. ;
Du L. ;
Li C. .
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2021, 234