Enhanced Electrochemical Performance of Dual-Ion Batteries with T-Nb2O5/Nitrogen-Doped Three-Dimensional Porous Carbon Composites

被引:1
作者
Qi, Chen [1 ]
Ying, Duo [1 ]
Ma, Cheng [1 ]
Qiao, Wenming [1 ]
Wang, Jitong [1 ,2 ]
Ling, Licheng [1 ]
机构
[1] East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
[2] Guangxi Univ, Sch Chem & Chem Engn, Guangxi Key Lab Petrochem Resource Proc & Proc Int, Nanning 530004, Peoples R China
基金
中国国家自然科学基金; 上海市自然科学基金;
关键词
dual-ion batteries; Nb2O5; anode; structure design; Nitrogen doping; ANODE MATERIALS; INTERCALATION; NANOPARTICLES; NANOFIBERS;
D O I
10.3390/molecules30020227
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Niobium pentoxide (T-Nb2O5) is a promising anode material for dual-ion batteries due to its high lithium capacity and fast ion storage and release mechanism. However, T-Nb2O5 suffers from the disadvantages of poor electrical conductivity and fast cycling capacity decay. Herein, a nitrogen-doped three-dimensional porous carbon (RMF) was prepared for loading niobium pentoxide to construct a composite system with excellent electrochemical performance. The obtained T-Nb2O5/RMF composites have a well-developed pore structure and a high specific surface area of 1568.5 m(2) g(-1), which could effectively increase the contact area between the material and electrolyte, improving the electrode reaction and lithium-ion transfer diffusion. Nitrogen doping increased surface polarity, creating more active sites and accelerating the electrode reaction rate. The introduction of T-Nb2O5 imparted high power density and excellent cycling stability to the battery. The composites exhibited good electrochemical performance when used as dual-ion battery anode, with a stable cycle life of 207.2 mA h g(-1) at 1 A g(-1) current density after 650 cycles and great rate performance of 181.5 mA h g(-1) at 5A g(-1) was also obtained. This work provides the possibility for applying T-Nb2O5/RMF as an anode for a high-performance dual-ion battery.
引用
收藏
页数:16
相关论文
共 47 条
[1]  
Anjali A, 2024, NEXT MATER, V2, DOI [10.1016/j.nxmate.2024.100117, 10.1016/j.nxmate.2024.100117]
[2]   Emerging Solutions to Enable the Efficient Use of Sodium Metal Anodes: Progress and Perspectives [J].
Chen, Chong ;
Yao, Wenjiao ;
Tang, Yongbing .
ADVANCED FUNCTIONAL MATERIALS, 2024, 34 (11)
[3]   Fundamental Understanding and Optimization Strategies for Dual-Ion Batteries: A Review [J].
Chen, Chong ;
Lee, Chun-Sing ;
Tang, Yongbing .
NANO-MICRO LETTERS, 2023, 15 (01)
[4]   Pseudohexagonal Nb2O5 Anodes for Fast-Charging Potassium-Ion Batteries [J].
Chen, Guanxu ;
Chen, Jintao ;
Zhao, Siyu ;
He, Guanjie ;
Miller, Thomas S. .
ACS APPLIED MATERIALS & INTERFACES, 2023, 15 (13) :16664-16672
[5]   Enhancing the low-temperature performance in lithium ion batteries of Nb2O5 by combination of W doping and MXene addition [J].
Chen, Yao ;
Pu, Ziyan ;
Liu, Yuebin ;
Shen, Yuxi ;
Liu, Shimin ;
Liu, Di ;
Li, Yueming .
JOURNAL OF POWER SOURCES, 2021, 515
[6]   Formation of a Surficial Bifunctional Nanolayer on Nb2O5 for Ultrastable Electrodes for Lithium-Ion Battery [J].
Cheong, Jun Young ;
Kim, Chanhoon ;
Jung, Ji-Won ;
Yoon, Ki Ro ;
Cho, Su-Ho ;
Youn, Doo-Young ;
Jang, Hye-Yeon ;
Kim, Il-Doo .
SMALL, 2017, 13 (19)
[7]   Prospects for magnesium ion batteries: A compreshensive materials review [J].
Das, Akhila ;
Balakrishnan, Neethu T. M. ;
Sreeram, Pranav ;
Fatima, M. J. Jabeen ;
Joyner, Jarin D. ;
Thakur, Vijay Kumar ;
Pullanchiyodan, Abhilash ;
Ahn, Jou-Hyeon ;
Raghavan, Prasanth .
COORDINATION CHEMISTRY REVIEWS, 2024, 502
[8]   Stepwise reduction of graphene oxide and studies on defect-controlled physical properties [J].
Das, Poulomi ;
Ibrahim, Sk ;
Chakraborty, Koushik ;
Ghosh, Surajit ;
Pal, Tanusri .
SCIENTIFIC REPORTS, 2024, 14 (01)
[9]   Anode chemistry in calcium ion batteries: A review [J].
Deng, Xianming ;
Li, Linyuan ;
Zhang, Guobin ;
Zhao, Xu ;
Hao, Jing ;
Han, Cuiping ;
Li, Baohua .
ENERGY STORAGE MATERIALS, 2022, 53 :467-481
[10]   Insight on the conversion reaction mechanism of NiCo2S4@CNTs as anode materials for lithium ion batteries and sodium ion batteries [J].
Fan, Shanshan ;
Liu, Haiping ;
Bi, Sifu ;
Gao, Chao ;
Meng, Xiaohuan ;
Wang, Yingnan .
ELECTROCHIMICA ACTA, 2021, 388