Investigation of the reaction mechanism for supercritical H2O/CO2 gasification of coal

被引：0
作者：
Zhang, Fan [1 ,4 ]
Chen, Wenjing [2 ]
Wang, Shuzhong [3 ]
Yang, Jianqiao [3 ]
Li, Yanhui [3 ]
机构：
[1] Tsinghua Univ, Sichuan Energy Internet Res Inst, Energy Strategy & Low carbon Dev Res Ctr, Chengdu 610213, Peoples R China
[2] Chengdu Univ Informat Technol, Coll Resources & Environm, Chengdu 610225, Peoples R China
[3] Xi An Jiao Tong Univ, Sch Energy & Power Engn, Xian 710049, Peoples R China
[4] Tsinghua Univ, Dept Energy & Power Engn, Beijing 100084, Peoples R China
来源：
ENERGY | 2025年 / 320卷
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
Coal; Supercritical H 2 O/CO 2 gasification; FTIR; Raman; Structural parameters; Sample Ultimate analysis (wt.%) Proximate analysis (wt.%); HYDROGEN-PRODUCTION; WATER GASIFICATION; H-2; OXIDATION; PYROLYSIS; EVOLUTION;
D O I：
10.1016/j.energy.2025.135441
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Under the dual background that oxidation reaction is used as internal heat source for supercritical water gasification and CO2 utilization, the exploration of supercritical H2O/CO2 gasification reaction mechanism is conducive to the promotion of new gasification technology. Based on the active site mechanism and pore structure, the reaction mechanism of the supercritical H2O/CO2 gasification of coal at 550-650 degrees C is revealed. The results showed that CO2 and H2O were competition mechanism in the supercritical H2O/CO2 gasification process, in which the addition of CO2 would lead to the decrease of carbon gasification efficiency from 25.7 % to 20 %, but the appropriate amount of CO2 (initial CO2 coefficient N = 0.5) would increase the CH4 yield to 10.64 mol/kg. Therefore, the moderate amount of CO2 (N = 0.5) will promote the transfer of hydrogen element from the water phase to the gas phase, but the addition of excessive CO2 (N = 1) will lead to the transfer of hydrogen element from the gas phase to the water phase, oil phase and solid phase; the addition of CO2 will inhibit the aromatization process of coal, lead to the aggravation of the disorder degree of gasification residue, and CO2 is not conducive to pore development, which will reduce the pore surface roughness and enhance the homogeneity of pore structure. When the high-pressure pyrolysis temperature is 500 degrees C, the hydrogen yield of Char500 is higher and the maturity of organic matter in the gasification residue is higher.
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页数：11
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  • [1] Chen J., Wang Q., Xu Z., E J., Leng E., Zhang F., Et al., Process in supercritical water gasification of coal: a review of fundamentals, mechanisms, catalysts and element transformation, Energy Convers Manage, 237, (2021)
  • [2] Wei N., Xu D., Hao B., Guo S., Guo Y., Wang S., Chemical reactions of organic compounds in supercritical water gasification and oxidation, Water Res, 190, (2021)
  • [3] Ge Z., Guo S., Guo L., Cao C., Su X., Jin H., Hydrogen production by non-catalytic partial oxidation of coal in supercritical water: explore the way to complete gasification of lignite and bituminous coal, Int J Hydrogen Energy, 38, 29, pp. 12786-12794, (2013)
  • [4] Matamba T., Iglauer S., Keshavarz A., A progress insight of the formation of hydrogen rich syngas from coal gasification, J Energy Inst, 105, pp. 81-102, (2022)
  • [5] Rong S., Huang L., Wang R., Xu J., Peng Z., Chen Y., Et al., Corrosion behaviors of Ni-based and Fe-based alloys in supercritical water gasification with inorganic chloride salt, Corros Sci, 219, (2023)
  • [6] Zhang F., Wang S., Li Y., Chen W., Qian L., Thermodynamic analysis of a supercritical water gasification – oxidation combined system for sewage sludge treatment with cool wall reactor, Energy Convers Manage, 247, (2021)
  • [7] Guo L., Jin H., Lu Y., Supercritical water gasification research and development in China, J Supercrit Fluids, 96, pp. 144-150, (2015)
  • [8] Fiori L., Valbusa M., Castello D., Supercritical water gasification of biomass for H2 production: process design, Bioresour Technol, 121, pp. 139-147, (2012)
  • [9] Hantoko D., Yan M., Kanchanatip E., Adnan M.A., Antoni M.I., Et al., Supercritical water gasification of sewage sludge and combined cycle for H2 and power production – a thermodynamic study, Int J Hydrogen Energy, 44, 45, pp. 24459-24470, (2019)
  • [10] Jin H., Chen Y., Ge Z., Liu S., Ren C., Guo L., Hydrogen production by Zhundong coal gasification in supercritical water, Int J Hydrogen Energy, 40, 46, pp. 16096-16103, (2015)
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