A fully electrically driven hydrogen direct reduction process for zero-carbon green steel production

被引:0
|
作者
Liang, Zeng [1 ]
Zhang, Jianliang [1 ]
Li, Kejiang [1 ]
Shao, Lei [2 ]
Liu, Zhengjian [1 ]
Yang, Zonghao [1 ]
Jiang, Chunhe [3 ]
Ren, Shan [4 ]
Conejo, Alberto N. [1 ]
机构
[1] Univ Sci & Technol Beijing, Sch Met & Ecol Engn, 30 Xueyuan Rd, Beijing 100083, Peoples R China
[2] Northeastern Univ, Sch Met, Shenyang 110819, Peoples R China
[3] Univ Sci & Technol Beijing, Tech Support Ctr Prevent & Control Disastrous Acci, Beijing 100083, Peoples R China
[4] Xi An Jiao Tong Univ, Sch Energy & Power Engn, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China
基金
中国博士后科学基金; 中国国家自然科学基金; 北京市自然科学基金; 美国国家科学基金会;
关键词
TEMPERATURE-PROGRAMMED REDUCTION; IRON-OXIDES; MECHANISM; KINETICS; CONDUCTIVITY;
D O I
10.1039/d5gc00279f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
As one of the most promising pathways for producing zero-carbon green steel, hydrogen-based shaft furnaces face significant challenges related to the heating, transportation, and injection of high-temperature (950-1050 degrees C) H2. A production process that integrates induction heating with low-temperature hydrogen injection into the shaft furnace has been proposed. The feasibility of producing high-quality direct reduced iron (DRI) through hydrogen reduction via induction heating has been validated at the laboratory scale. Utilizing advanced in situ XRD analysis, the reduction pathway of iron oxides (Fe2O3 -> Fe3O4 -> FeO -> Fe) was clearly delineated, revealing the phase transition processes at each stage. Induction heating performance varies significantly with the reduction degree: Fe2O3 initially lacks heating capability, but reduction to Fe3O4 enhances magnetic properties, improving efficiency. Further reduction to FeO decreases efficiency, which rises again when metallic Fe becomes the dominant phase. Under induction heating, DRI samples reach over 900 degrees C within seconds, demonstrating strong heating potential. Integrating electrolytic hydrogen generation with induction heating produces high-quality DRI, achieving a 96.04% reduction in 40 minutes at 750 degrees C. These findings establish a fully green, electric-driven direct reduction system, eliminating the need for high-temperature reducing gases and advancing sustainable iron production.
引用
收藏
页码:4766 / 4778
页数:13
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