A review of metal-organic frameworks and polymers in mixed matrix membranes for CO2 capture

Polymeric membranes offer an appealing solution for sustainable CO2 capture, with potential for large-scale deployment. However, balancing high permeability and selectivity is an inherent challenge for pristine membranes. To address this challenge, the development of mixed matrix membranes (MMMs) is a promising strategy. MMMs are obtained by carefully integrating porous nano- fillers into polymeric matrices, enabling the simultaneous enhancement of selectivity and permeability. In particular, metal-organic frameworks (MOFs) have gained recognition as MMM fillers for CO2 capture. Here, a review of the current state, recent advancements, and challenges in the fabrication and engineering of MMMs with MOFs for selective CO2 capture is proposed. Key considerations and promising research directions to fully exploit the gas separation potential of MOF-based MMMs in CO2 capture applications are highlighted.