Optimizing Supercapacitor Performance with LSCF, ST, BST, and Coconut Shell Activated Carbon

被引:0
作者
Lurdhumary, J. [1 ]
Princye, P. Hosanna [2 ]
Prakash, Arul [3 ]
Sangeetha, L. [4 ]
Kumar, G. S. V. Seshu [5 ]
Maheswari, S. [6 ]
Kirubakaran, D. [7 ]
Umaralikhan, L. [8 ]
Vijayan, V. [9 ]
机构
[1] Sri Sai Ram Inst Technol, Dept Elect & Commun Engn, Chennai 600044, Tamil Nadu, India
[2] Sri Sairam Coll Engn, Dept Elect & Commun Engn, Bangalore 562106, Karnataka, India
[3] Sri Sairam Engn Coll, Dept Mech Engn, Chennai 600044, Tamil Nadu, India
[4] Saveetha Engn Coll, Dept Phys, Chennai 602105, Tamil Nadu, India
[5] SRKR Engn Coll, Dept Mech Engn, Bhimavaram 534204, Andhra Pradesh, India
[6] Kongu Engn Coll, Dept Elect & Elect Engn, Perundurai 638060, Tamil Nadu, India
[7] St Josephs Inst Technol, Dept Elect & Elect Engn, Chennai 600119, Tamil Nadu, India
[8] Jamal Mohamed Coll Autonomous, Dept Phys, Trichy 620020, Tamil Nadu, India
[9] K Ramakrishnan Coll Technol, Dept Mech Engn, Tiruchirappalli 621112, India
关键词
Spray pyrolysis; Activated carbon; Perovskite materials; Ferroelectrics; Supercapacitor Energy storage; MECHANICAL-BEHAVIOR; NI FOAM; PEROVSKITE; COMPOSITES;
D O I
10.14447/jnmes.v27i3.a07
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Emerging electrochemical devices including fuel cells, supercapacitors, and lithium-ion batteries are crucial for energy conservation, storage, and transfer. When looking for a replacement for traditional batteries, electrochemical supercapacitors offer a viable option due to their long cycling life and high power supply capabilities. Problems with their high production cost and poor energy density, however, prevent their widespread use. Presenting here is the novel merging of perovskite (LSCF, BST, ST) and CSAC (coconut shell-based activated carbon) materials produced in a thin layer by spray pyrolysis. The integration of the electroactive medium with the double-layer electrode in electrochemical supercapacitors expands upon earlier research. Using cyclic voltammetry, electrochemical impedance spectroscopy, galvanostatic charge/discharge profiling, and modeling of the experimental data, the performance and dynamic electrical behavior of different supercapacitor topologies were examined for utilization in power applications. These structures, which were made of cotton lint and organic cellulose were shaped like asymmetric coin cells. Mixing BST with cellulose results in supercapacitors with 300 F/g specific capacitances, energy densities of 6.7 Wh/kg, power densities of 600 W/kg, and the ability to preserve over 95% of their initial capacitance even after multiple charging and discharging cycles. Based on these promising features, we demonstrated the practicality of our supercapacitor approach by connecting two identical cells and briefly powering a yellow LED. This breakthrough will pave the way for the development of supercapacitors that are more pliable, lightweight, and affordable, and which may have better energy-storing capabilities and longer lifespans.
引用
收藏
页码:215 / 226
页数:12
相关论文
共 38 条
[1]   Advanced materials and technologies for hybrid supercapacitors for energy storage - A review [J].
Afir, Ahmed ;
Rahman, Sheikh M. H. ;
Azad, Atia Tasfiah ;
Zaini, Juliana ;
Islan, Md Aminul ;
Azad, Abul Kalam .
JOURNAL OF ENERGY STORAGE, 2019, 25
[2]   Tailoring the Perovskite Structure to Acquire an Inorganic La2NiCrO6 Double Perovskite as an Efficient Energy Storage Application by Varying Molar Concentrations of Citric Acid [J].
Ajin, I. ;
Balamurugan, R. ;
Bose, A. Chandra .
ACS APPLIED ENERGY MATERIALS, 2023, 6 (18) :9764-9777
[3]   Development of Nanocomposite based Antimicrobial Cotton Fabrics Impregnated by Nano SiO2 Loaded AgNPs Derived from Eragrostis Teff straw [J].
Amibo T.A. ;
Beyan S.M. ;
Mustefa M. ;
Sundramurthy V.P. ;
Bayu A.B. .
Materials Research Innovations, 2022, 26 (07) :405-414
[4]   The effect of B - site cation on the supercapacitive properties of LaBO3 (B = Cr, Mn, Fe and Co) porous perovskites [J].
Ashok, C. Shyamli ;
Vazhayil, Ashalatha ;
Vinaykumar, R. ;
Thomas, Jasmine ;
Jeffery, A. Anto ;
Hasan, Imran ;
Thomas, Nygil ;
Yadav, Akhilesh Kumar ;
Ahn, Young-Ho .
JOURNAL OF ENERGY STORAGE, 2024, 86
[5]  
Bothiraj T., 2022, Materials Today: Proceedings, P2239, DOI 10.1016/j.matpr.2022.08.441
[6]   Symmetric/Asymmetric Supercapacitor Based on the Perovskite-type Lanthanum Cobaltate Nanofibers with Sr-substitution. [J].
Cao, Yi ;
Lin, Baoping ;
Sun, Ying ;
Yang, Hong ;
Zhang, Xueqin .
ELECTROCHIMICA ACTA, 2015, 178 :398-406
[7]   Application of a clustered countercurrent-flow micro-channel reactor in the preparation of KMnF3 perovskite for asymmetric supercapacitors [J].
Cheng, Kun-Peng ;
Gu, Ren-Jie ;
Wen, Li-Xiong .
RSC ADVANCES, 2020, 10 (20) :11681-11693
[8]  
Dinesh S., 2016, Asian Journal of Research in Social Sciences and Humanities, V6, P849, DOI [10.5958/2249-7315.2016.00654.7, DOI 10.5958/2249-7315.2016.00654.7]
[9]  
Dinesh S., 2016, Asian Journal of Research in Social Sciences and Humanities, V6, P179, DOI [10.5958/2249-7315.2016.01006.6, DOI 10.5958/2249-7315.2016.01006.6]
[10]   Zinc doping effect on the structural and electrochemical properties of LaCoO3 perovskite as a material for hybrid supercapacitor electrodes [J].
Hadji, Fawzi ;
Omari, Mahmoud ;
Mebarki, Mourad ;
Gabouze, Noureddine ;
Layadi, Abdelhamid .
JOURNAL OF ALLOYS AND COMPOUNDS, 2023, 942