Visible-Light Photocatalytic Nucleophilic Addition of 4-Pyridylphosphonium Salts to CO2 and Carbonyl Compounds

被引：0
|
作者：
Cui, Wenwen [1 ]
Li, Bin [1 ]
Wang, Baiquan [1 ,2 ]
机构：
[1] Nankai Univ, Coll Chem, Frontiers Sci Ctr New Organ Matter, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ORGANIC LETTERS | 2025年 / 27卷 / 13期
基金：
中国国家自然科学基金;
关键词：
CARBOXYLATION; PYRIDINES; FUNCTIONALIZATION; ARYLATION; BONDS;
D O I：
10.1021/acs.orglett.5c00786
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A visible-light photocatalytic nucleophilic addition of 4-pyridylphosphonium salts to CO2 and carbonyl compounds is reported. The reaction has mild reaction conditions, good functional group tolerance, and a wide range of substrates. Mechanistic studies show that the reaction may occur through the pyridylphosphonium salt radical anion, pyridyl radical, and pyridyl anion intermediates. By combination with C4-H phosphination, this method can be applied to the late-stage C-H functionalization of drugs containing a pyridine unit.
引用
收藏
页码：3390 / 3395
页数：6
相关论文
共 50 条
  • [21] Cu-doped SnS2 nanosheets with superior visible-light photocatalytic CO2 reduction performance
    Di, Tingmin
    Cao, Tengfei
    Liu, Han
    Wang, Shenggao
    Zhang, Jun
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2023, 25 (06) : 5196 - 5202
  • [22] Enhanced visible-light photocatalytic CO2 reduction performance of ZnIn2S4 microspheres by using CeO2 as cocatalyst
    Yang, Chao
    Li, Qin
    Xia, Yang
    Lv, Kangle
    Li, Mei
    APPLIED SURFACE SCIENCE, 2019, 464 : 388 - 395
  • [23] PHOTOREDUCTION OF CO2 TO CH4 IN AQUEOUS-SOLUTIONS USING VISIBLE-LIGHT
    MAIDAN, R
    WILLNER, I
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (25) : 8100 - 8101
  • [24] Hydrogen-Bonded Organic Framework Ultrathin Nanosheets for Efficient Visible-Light Photocatalytic CO2 Reduction
    Yu, Baoqiu
    Meng, Ting
    Ding, Xu
    Liu, Xiaolin
    Wang, Hailong
    Chen, Baotong
    Zheng, Tianyu
    Li, Wen
    Zeng, Qingdao
    Jiang, Jianzhuang
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (43)
  • [25] VISIBLE-LIGHT INDUCED PHOTOCATALYTIC FIXATION OF CO2 INTO BENZOPHENONE USING POLY(P-PHENYLENE) AS A PHOTOCATALYST
    OGATA, T
    HIRANAGA, K
    MATSUOKA, S
    WADA, Y
    YANAGIDA, S
    CHEMISTRY LETTERS, 1993, (06) : 983 - 984
  • [26] A cryptand-like Ti-coordination compound with visible-light photocatalytic activity in CO2 storage
    Liu, Yanshu
    Zhang, Guanyun
    Wang, Dexin
    Chen, Guanjie
    Gao, Fangfang
    Tung, Chen-Ho
    Wang, Yifeng
    DALTON TRANSACTIONS, 2024, 53 (05) : 1989 - 1998
  • [27] Significant Effect of Crystallization of Polymeric Carbon Nitride on Photoconductivity and Photocatalytic Activity for Visible-Light CO2 Reduction
    Tanaka, Toshiya
    Zhang, Chao
    Nakada, Ryuichi
    Onodera, Jo
    Ishiwari, Fumitaka
    Okazaki, Megumi
    Saeki, Akinori
    Ishitani, Osamu
    Zhang, Guigang
    Maeda, Kazuhiko
    CCS CHEMISTRY, 2024, 6 (12): : 2940 - 2949
  • [28] Unique Zinc Germanium Oxynitride Hyperbranched Nanostructures with Enhanced Visible-Light Photocatalytic Activity for CO2 Reduction
    Liu, Qi
    Xu, Miao
    Zhou, Beibei
    Liu, Rongmei
    Tao, Feng
    Mao, Guobing
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (15) : 2195 - 2200
  • [29] Tunable Syngas Synthesis from Photocatalytic CO2 Reduction Under Visible-Light Irradiation by Interfacial Engineering
    Conghui Qiu
    Sha Bai
    Wenjing Cao
    Ling Tan
    Junyan Liu
    Yufei Zhao
    Yu-Fei Song
    Transactions of Tianjin University, 2020, (05) : 352 - 361
  • [30] Nanoarchitecture engineering of crumpled polymeric carbon nitride nanosheets for efficient visible-light photocatalytic CO2 reduction
    Guo, Yongkang
    An, Sufeng
    Gideon, Ocran Abaidoo
    An, Yonglin
    Li, Keyan
    Wang, Xuehai
    Guo, Xinwen
    APPLIED SURFACE SCIENCE, 2023, 627
12345