Crystal structure and Hirshfeld surface analysis of trichlorido(1,10-phenanthroline-κ2N,N')phenyltin(IV)

被引：0

作者：

Benlatreche, Tarek ^{[1
,2
]}

Bensegueni, Mohamed Abdellatif ^{[1
]}

Denes, Georges ^{[3
]}

Golhen, Stephane ^{[4
]}

Merazig, Hocine ^{[1
]}

机构：

[1] Univ Constantine 1 Mentouri Bros, URCHEMS, Environm & Struct Mol Chem Res Unit, Fac Exact Sci, Meerut 250001, Uttar Pradesh, India

[2] Natl Higher Sch Hydraul Abdellah Arbaoui, Blida, Algeria

[3] Concordia Univ, Lab Solid State Chem & Mossbauer Spectroscopy, Dept Chem & Biochem, Montreal, PQ, Canada

[4] Univ Rennes, CNRS, Rennes Inst Chem Sci, UMR 6226, Rennes, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2024年 / 80卷

关键词：

crystal structure; Hirshfeld surface analysis; C-H center dot center dot center dot Cl hydrogen bond; phenanthroline; tin(IV); COMPLEXES; 1,10-PHENANTHROLINE; LIGANDS;

D O I：

10.1107/S2056989024009150

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Sn(C6H5)Cl-3(C12H8N2)], which was obtained by the reaction between 1,10-phenanthroline and phenyltin trichloride in methanol, exhibits intramolecular hydrogen-bonding interactions involving the chlorine and hydrogen atoms. Crystal cohesion is ensured by intermolecular C-H center dot center dot center dot Cl hydrogen bonds, as well as Y-X center dot center dot center dot pi and pi-stacking interactions involving three different aromatic rings with centroid-centroid distances of 3.6605 (13), 3.9327 (14) and 3.6938 (12) angstrom degrees]. Hirshfeld surface analysis and the associated two-dimensional fingerprint plots reveal significant contributions from H center dot center dot center dot H (30.7%), Cl center dot center dot center dot H/H center dot center dot center dot Cl (32.4%), and C center dot center dot center dot H/H center dot center dot center dot C (24.0%) contacts to the crystal packing while the C...C (6.2%), C center dot center dot center dot Cl/Cl center dot center dot center dot C (4.1%), and N center dot center dot center dot H/H center dot center dot center dot N (1.7%) interactions make smaller contributions.

引用

页码：1039 / +

页数：10

共 30 条

[21] EDGE STATES IN OPEN ANTIFERROMAGNETIC HEISENBERG-CHAINS [J].

QIN, SJ ;

NG, TK ;

SU, ZB .

PHYSICAL REVIEW B, 1995, 52 (17) :12844-12848

[22] Tin(IV) complexes of 2-benzoylpyridine N(4)-phenyl-thiosemicarbazone:: spectral characterization, structural studies and antifungal activity [J].

Rebolledo, AP ;

de Lima, GM ;

Gambi, LN ;

Speziali, NL ;

Maia, DF ;

Pinheiro, CB ;

Ardisson, JD ;

Cortés, ME ;

Beraldo, H .

APPLIED ORGANOMETALLIC CHEMISTRY, 2003, 17 (12) :945-951

[23] INDUSTRIAL APPLICATIONS OF ORGANOTIN COMPOUNDS [J].

ROSS, A .

ANNALS OF THE NEW YORK ACADEMY OF SCIENCES, 1965, 125 (A1) :107-&

[24] 1,10-PHENANTHROLINE - A VERSATILE LIGAND [J].

SAMMES, PG ;

YAHIOGLU, G .

CHEMICAL SOCIETY REVIEWS, 1994, 23 (05) :327-334

[25]

Sheldrick G. M., ACTA CRYST, VA71, P3

[26]

Sheldrick G.M., 1993, SHELXL 93 PROGRAM CR

[27] Hirshfeld surface analysis [J].

Spackman, Mark A. ;

Jayatilaka, Dylan .

CRYSTENGCOMM, 2009, 11 (01) :19-32

[28] CrystalExplorer: a program for Hirshfeld surface analysis, visualization and quantitative analysis o molecular crystals [J].

Spackman, Peter R. ;

Turner, Michael J. ;

McKinnon, Joshua J. ;

Wolff, Stephen K. ;

Grimwood, Daniel J. ;

Jayatilaka, Dylan ;

Spackman, Mark A. .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2021, 54 :1006-1011

[29] Cellular Basis of Organotin(IV) Derivatives as Anticancer Metallodrugs: A Review [J].

Syed Annuar, Sharifah Nadhira ;

Kamaludin, Nurul Farahana ;

Awang, Normah ;

Chan, Kok Meng .

FRONTIERS IN CHEMISTRY, 2021, 9

[30] Dichloridobis(4-chlorobenzyl-κC)(1,10-phenanthroline-κ2N,N′)tin(IV) [J].

Tan, Chui Lian ;

Lo, Kong Mun ;

Ng, Seik Weng .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 :M717-U304

← 1 2 3 →