Palladium(II) 1,3-bis(aryl)triazenide complexes: Synthesis and structural characterization

被引：0

作者：

Rios-Moreno, Gustavo ^{[1
]}

Alvarado-Rodriguez, Jose G. ^{[2
]}

Cortes-Llamas, Sara A. ^{[3
]}

Miranda-Soto, Valentin ^{[4
]}

Aguirre-Hernandez, Gerardo ^{[4
]}

Muro-Herrera, Sara ^{[1
]}

Quinones-Reyes, Guillermo ^{[1
]}

Felix-Flores, Ma. Guadalupe ^{[1
]}

Lozada-Rodriguez, Leticia ^{[1
]}

机构：

[1] Univ Autonoma Zacatecas, Unidaa Acad Ciencias Quim, Campus UAZ Siglo XXI,Carretera Zacatecas Guadalaja, Zacatecas 98160, Zac, Mexico

[2] Univ Autonoma Estado Hidalgo, Unidad Univ, Km 4-5 Carretera Pachuca Tulancingo, Mineral De La Reforma 42184, Hidalgo, Mexico

[3] Univ Guadalajara, Ctr Univ Ciencias Exactas Ingn, Dept Quim, Blvd Marcelino Garcia Barragan 1421, Guadalajara 44430, Jalisco, Mexico

[4] Tecnol Nacl Mexico, Inst Tecnol Tijuana, Ctr Grad & Invest Quim, Tijuana 22444, Baja California, Mexico

来源：

INORGANICA CHIMICA ACTA | 2025年 / 578卷

关键词：

Triazenes; Triazenides; palladium(II) complex; Crystal structure; TRIAZENIDE COMPLEXES; DINUCLEAR PALLADIUM(I); HYDROGEN EVOLUTION; LIGANDS; REACTIVITY; PLATINUM; BEHAVIOR; COPPER; ACID;

D O I：

10.1016/j.ica.2025.122539

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Palladium(II) 1,3-bis(aryl)triazenide complexes [Pd(PPh3)2Cl(ArNNNAr')], Ar = p-COCH3-C6H4; 2a Ar ' C6H5; 2b Ar '= o-OCH3-C6H4; 2c Ar '= o-OCH2CH3-C6H4; 2d Ar '= o-SCH3-C6H4 were obtained by reaction of [PdCl2(PPh3)2] with the corresponding triazenides. Complexes 2a-2d were characterized by IR, MS-ESI, NMR and X-ray diffraction techniques. In all cases, triazenides are coordinated to Pd(II) in a monodentate mode. In these complexes, it was observed that the Pd-N linking preference between the two terminal nitrogen atoms of the triazenide ligands, is determined by steric and inductive factors.

引用

页数：9

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