Observation of Enhanced Long-Range Ferromagnetic Order in B-Site Ordered Double Perovskite Oxide Cd2CrSbO6

被引：0

作者：

Liu, Shengjie ^{[1
,2
]}

Wang, Xiao ^{[1
]}

Deng, Zunyi ^{[3
]}

Ye, Xubin ^{[1
]}

Pan, Zhao ^{[1
]}

Lu, Dabiao ^{[1
,4
]}

Zhao, Haoting ^{[1
,4
]}

Zhang, Jie ^{[1
,4
]}

Pi, Maocai ^{[1
,4
]}

Hu, Zhiwei ^{[5
]}

Chen, Chien-Te ^{[6
]}

Dong, Cheng ^{[1
]}

Shen, Yao ^{[1
]}

Cui, Tian ^{[2
]}

Huang, Yanping ^{[2
]}

Hong, Jiawang ^{[3
]}

Chi, Zhenhua ^{[7
]}

Long, Youwen ^{[1
,4
,8
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100190, Peoples R China

[2] Ningbo Univ, Inst High Pressure Phys, Sch Phys Sci & Technol, Ningbo 315211, Peoples R China

[3] Beijing Inst Technol, Sch Aerosp Engn, Beijing 100081, Peoples R China

[4] Univ Chinese Acad Sci, Sch Phys Sci, Beijing 100049, Peoples R China

[5] Max Planck Inst Chem Phys Solids, D-01187 Dresden, Germany

[6] Natl Synchrotron Radiat Res Ctr NSRRC, Hsinchu 30076, Taiwan

[7] Chinese Acad Sci, Inst Plasma Phys, HFIPS, Hefei 230031, Peoples R China

[8] Songshan Lake Mat Lab, Dongguan 523808, Guangdong, Peoples R China

来源：

INORGANIC CHEMISTRY | 2024年 / 63卷 / 42期

基金：

国家重点研发计划; 北京市自然科学基金; 中国博士后科学基金; 中国国家自然科学基金;

关键词：

TOTAL-ENERGY CALCULATIONS; MAGNETIC-PROPERTIES; A-SITE; MAGNETORESISTANCE; PHASE;

D O I：

10.1021/acs.inorgchem.4c03543

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A B-site ordered double perovskite oxide Cd2CrSbO6 was synthesized under high-pressure and high-temperature conditions. The compound crystallizes to a monoclinic structure with a space group of P2(1)/n. The charge configuration is confirmed to be that of Cd2+/Cr3+/Sb5+. The magnetic Cr3+ ions form a tetrahedral structural frustrated lattice, while a long-range ferromagnetic phase transition is found to occur at T-C = 16.5 K arising from the superexchange interaction via the Cr-O-Cd-O-Cr pathway. Electrical transport measurements indicate that Cd2CrSbO6 is an insulator that can be described by the Mott 3D variable range hopping mechanism. First-principles calculations reproduce well the ferromagnetic and insulating ground state of Cd2CrSbO6 with an energy band gap of 1.55 eV. The intrinsic ferromagnetic insulating nature qualifies Cd2CrSbO6 as a promising candidate for possible spintronics applications.

引用

页码：19964 / 19971

页数：8

共 50 条

[1] Long-Range Antiferromagnetic Ordering in B-Site Ordered Double Perovskite Ca2ScOsO6
Russell, David D.
Neer, Abbey J.
Melot, Brent C.
Derakhshan, Shahab
INORGANIC CHEMISTRY, 2016, 55 (05) : 2240 - 2245
[2] Pressure-induced incommensurate antiferromagnetic order in a ferromagnetic B-site ordered double-perovskite Lu2NiMnO6
Terada, Noriki
Colin, Claire, V
Qureshi, Navid
Hansen, Thomas C.
Matsubayashi, Kazuyuki
Uwatoko, Yoshiya
Belik, Alexei A.
PHYSICAL REVIEW B, 2020, 102 (09)
[3] Multiferroicity in B-site ordered double perovskite Y2MnCrO6
Fang Yong
Yan Shi-Ming
Qiao Wen
Wang Wei
Wang Dun-Hui
Du You-Wei
CHINESE PHYSICS B, 2014, 23 (11)
[4] Multiferroicity in B-site ordered double perovskite Y2MnCrO6
房勇
颜士明
乔文
王伟
王敦辉
都有为
Chinese Physics B, 2014, 23 (11) : 527 - 530
[5] Evidence of long-range ferromagnetic order and spin frustration effects in the double perovskite La2CoMnO6
Madhogaria, R. P.
Das, R.
Clements, E. M.
Kalappattil, V
Phan, M. H.
Srikanth, H.
Dang, N. T.
Kozlenko, D. P.
Bingham, N. S.
PHYSICAL REVIEW B, 2019, 99 (10)
[6] Magnetic properties and giant cryogenic magnetocaloric effect in B-site ordered antiferromagnetic Gd2MgTiO6 double perovskite oxide
Zhang, Yikun
Tian, Yun
Zhang, Zhenqian
Jia, Youshun
Zhang, Bin
Jiang, Minqiang
Wang, Jiang
Ren, Zhongming
ACTA MATERIALIA, 2022, 226
[7] Synthesis, structure, and magnetic properties of SrLaMnSbO6:: A new B-Site ordered double perovskite
Mandal, Tapas Kumar
Abakumov, Artem M.
Lobanov, Maxim V.
Croft, Mark
Poltavets, Viktor V.
Greenblatt, Martha
CHEMISTRY OF MATERIALS, 2008, 20 (14) : 4653 - 4660
[8] Crystal structure and properties of the magnetically frustrated B-site ordered Sr2CaOsO6 double perovskite
Thakur, Gohil S.
Schnelle, Walter
Jansen, Martin
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2023, 649 (18):
[9] The preparation, and structural and multiferroic properties of B-site ordered double-perovskite Bi2FeMnO6
Sun, Lin
Fang, Yue-Wen
He, Jun
Zhang, Yuanyuan
Qi, Ruijuan
He, Qing
Huang, Rong
Xiang, Pinghua
Tang, Xiao-Dong
Yang, Pingxiong
Chu, Junhao
Chu, Ying-Hao
Duan, Chun-Gang
JOURNAL OF MATERIALS CHEMISTRY C, 2017, 5 (22) : 5494 - 5500
[10] Effect of B-Site Ordering on the Magnetic Order in Multifunctional La2NiMnO6Double Perovskite*
Yang, Dexin
Jiang, Rui
Zhang, Yaohua
Zhang, Hui
Lei, Senlin
Yang, Tao
Hu, Xiaoshi
Huang, Shuai
Ge, Jingyuan
Su, Kunpeng
Wang, Haiou
Huo, Dexuan
CHINESE PHYSICS LETTERS, 2020, 37 (10)

← 1 2 3 4 5 →