Halide-free deep eutectic solvents constructed from natural compounds for converting carbon dioxide to cyclic carbonate

被引：1

作者：

Yu, Wen-Wang ^{[1
]}

Meng, Xiang-Guang ^{[1
]}

Li, Wen ^{[1
]}

Zhou, Jie ^{[1
]}

Ma, Xian-Jian ^{[1
]}

Chu, Dan-Dan ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Key Lab Green Chem & Technol, Minist Educ, Chengdu 610064, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 16期

关键词：

Cycloaddition - Organic solvents;

D O I：

10.1039/d4cc06282e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Halide-free deep eutectic solvents (DESs) derived from natural biological compounds were used to gently catalyze the cycloaddition reaction between CO2 and epoxides, with a TOF of 645 h-1. The DFT calculation result was in good agreement with the experiment result, indicating that the ring closure process was the rate-determining step.

引用

收藏

页码：3391 / 3394

页数：4

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