Sulfobetaine ionic liquid crystals based on strong acids: phase behavior and electrochemistry

被引：0

作者：

Lange, Alyna ^{[1
]}

Kapernaum, Nadia ^{[2
]}

Wojnarowska, Zaneta ^{[3
]}

Holtzheimer, Lea ^{[1
]}

Mies, Stefan ^{[1
]}

Williams, Vance ^{[4
]}

Giesselmann, Frank ^{[2
]}

Taubert, Andreas ^{[1
]}

机构：

[1] Univ Potsdam, Inst Chem, Karl Liebknecht Str 24-25, D-14476 Potsdam, Germany

[2] Univ Stuttgart, Inst Phys Chem, Pfaffenwaldring 55, D-70569 Stuttgart, Germany

[3] Univ Silesia Katowice, Inst Phys, PL-41500 Chorzow, Poland

[4] Simon Fraser Univ, Dept Chem, 8888 Univ Dr, Burnaby, BC, Canada

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2025年 / 27卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

TEMPERATURE-DEPENDENCE; SELF-ORGANIZATION; CUBIC MESOPHASE; CONDUCTIVITY; TRANSPORT; ELECTROLYTES; ANION; TRANSITIONS; MEMBRANES; DYNAMICS;

D O I：

10.1039/d4cp03060e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A group of new zwitterion based ionic liquid crystals (ILCs) have been synthesized. Depending on the counter anion (mesylate or hydrogen sulfate) the phase behavior of the resulting ILCs is quite different. Mesylate based ILCs show complex phase behavior with multiple phases depending on the alkyl chain length. In contrast, hydrogen sulfate based systems always exhibit Colr phases irrespective of the alkyl chain length. The latter show much larger ILC mesophase windows and are thermally stable up to ca. 200 degrees C. All ILCs show reasonable ionic conductivities of up to 10-4 S cm-1 at elevated temperatures, making these ILCs candidates for intermediate temperature ionic conductors.

引用

页码：844 / 860

页数：17

共 50 条

[31] Influence of Acetonitrile on the Electrochemical Behavior of Ionic Liquid-Based Supercapacitors [J].

Karamanova, Boryana ;

Soserov, Luybomir ;

Lefterova, Elefteria ;

Stankulov, Toma ;

Stoyanova, Antonia .

BATTERIES-BASEL, 2024, 10 (08)

[32] Thermotropic Columnar Liquid Crystals Based on Wedge-Shaped Phenylphosphonic Acids [J].

Kumar, K. R. Sunil ;

Gupta, Monika ;

Sakamoto, Takeshi ;

Kato, Takashi .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2019, 92 (09) :1450-1452

[33] Thermosensitive Phase Separation Behavior of Poly(benzyl methacrylate)/Solvate Ionic Liquid Solutions [J].

Kobayashi, Yumi ;

Kitazawa, Yuzo ;

Hashimoto, Kei ;

Ueki, Takeshi ;

Kokubo, Hisashi ;

Watanabe, Masayoshi .

LANGMUIR, 2017, 33 (49) :14105-14114

[34] Dynamic Phase Behavior of Surface-Active Fluorinated Ionic Liquid Epoxidation Catalysts [J].

Hegelmann, Markus ;

Zuber, Julian ;

Luibl, Johannes ;

Jandl, Christian ;

Korth, Wolfgang ;

Jess, Andreas ;

Cokoja, Mirza .

CHEMISTRY-A EUROPEAN JOURNAL, 2024, 30 (69)

[35] Strong Tendency of Homeotropic Alignment and Anisotropic Lithium Ion Conductivity of Sulfonate Functionalized Zwitterionic Imidazolium Ionic Liquid Crystals [J].

Rondla, Rohini ;

Lin, Joseph C. Y. ;

Yang, C. T. ;

Lin, Ivan J. B. .

LANGMUIR, 2013, 29 (37) :11779-11785

[36] Study of the mesomorphic behaviour through the structure modification of azo and acetylene pyridinium and imidazolium-based ionic liquid crystals [J].

Filippi, Natan Glauber ;

Mezalira, Daniela Zambelli ;

Ovalle, Saul ;

Westphal, Eduard .

LIQUID CRYSTALS, 2016, 43 (13-15) :2163-2190

[37] Liquid-solid-liquid phase transition hysteresis loops in the ionic conductivity of ten imidazolium-based ionic liquids [J].

Vila, J. ;

Fernandez-Castro, B. ;

Rilo, E. ;

Carrete, J. ;

Dominguez-Perez, M. ;

Rodriguez, J. R. ;

Garcia, M. ;

Varela, L. M. ;

Cabeza, O. .

FLUID PHASE EQUILIBRIA, 2012, 320 :1-10

[38] Phase Behavior and Ionic Conductivity of Concentrated Solutions of Polystyrene-Poly(ethylene oxide) Diblock Copolymers in an Ionic Liquid [J].

Simone, Peter M. ;

Lodge, Timothy P. .

ACS APPLIED MATERIALS & INTERFACES, 2009, 1 (12) :2812-2820

[39] Colloid and nanoparticle-driven phase behavior in weakly perturbed nematic liquid crystals [J].

Holbl, Arbresha ;

Pal, Kaushik ;

Ahmad, Irfan ;

Asiri, Hatem Mohammed A. ;

Kralj, Samo .

JOURNAL OF MOLECULAR STRUCTURE, 2024, 1307

[40] Phase Behavior and Conductivity of Sulfonated Block Copolymers Containing Heterocyclic Diazole-Based Ionic Liquids [J].

Kim, Onnuri ;

Kim, Sung Yeon ;

Ahn, Hyungmin ;

Kim, Chang Woo ;

Rhee, Young Min ;

Park, Moon Jeong .

MACROMOLECULES, 2012, 45 (21) :8702-8713

← 1 2 3 4 5 →