Sulfobetaine ionic liquid crystals based on strong acids: phase behavior and electrochemistry

被引：0

作者：

Lange, Alyna ^{[1
]}

Kapernaum, Nadia ^{[2
]}

Wojnarowska, Zaneta ^{[3
]}

Holtzheimer, Lea ^{[1
]}

Mies, Stefan ^{[1
]}

Williams, Vance ^{[4
]}

Giesselmann, Frank ^{[2
]}

Taubert, Andreas ^{[1
]}

机构：

[1] Univ Potsdam, Inst Chem, Karl Liebknecht Str 24-25, D-14476 Potsdam, Germany

[2] Univ Stuttgart, Inst Phys Chem, Pfaffenwaldring 55, D-70569 Stuttgart, Germany

[3] Univ Silesia Katowice, Inst Phys, PL-41500 Chorzow, Poland

[4] Simon Fraser Univ, Dept Chem, 8888 Univ Dr, Burnaby, BC, Canada

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2025年 / 27卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

TEMPERATURE-DEPENDENCE; SELF-ORGANIZATION; CUBIC MESOPHASE; CONDUCTIVITY; TRANSPORT; ELECTROLYTES; ANION; TRANSITIONS; MEMBRANES; DYNAMICS;

D O I：

10.1039/d4cp03060e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A group of new zwitterion based ionic liquid crystals (ILCs) have been synthesized. Depending on the counter anion (mesylate or hydrogen sulfate) the phase behavior of the resulting ILCs is quite different. Mesylate based ILCs show complex phase behavior with multiple phases depending on the alkyl chain length. In contrast, hydrogen sulfate based systems always exhibit Colr phases irrespective of the alkyl chain length. The latter show much larger ILC mesophase windows and are thermally stable up to ca. 200 degrees C. All ILCs show reasonable ionic conductivities of up to 10-4 S cm-1 at elevated temperatures, making these ILCs candidates for intermediate temperature ionic conductors.

引用

页码：844 / 860

页数：17

共 50 条

[21] Self-assembly, mesomorphic behavior, and ionic conductivity of polymerized ionic liquid crystals with a threshold switching characteristic [J].

Tang, Xinqiao ;

Chang, Xiaolong ;

Zhu, Boyan ;

Cui, Luan ;

Jiang, Beihong ;

Meng, Fanbao ;

Yan, Guiyang .

POLYMERS FOR ADVANCED TECHNOLOGIES, 2022, 33 (12) :4317-4329

[22] Ionic liquid crystals based on 1-alkyl-3-methylimidazolium cations and perfluorinated sulfonylimide anions [J].

Li, Ting ;

Xu, Fei ;

Shi, Wei .

CHEMICAL PHYSICS LETTERS, 2015, 628 :9-15

[23] Tuning Binary Ionic Liquid Mixtures: Linking Alkyl Chain Length to Phase Behavior and Ionic Conductivity [J].

Fox, Eric T. ;

Weaver, Joshua E. F. ;

Henderson, Wesley A. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (08) :5271-5275

[24] Dicationic imidazolium-based ionic liquids and ionic liquid crystals with variously positioned fluoro substituents [J].

Li, Xiaoju ;

Bruce, Duncan W. ;

Shreeve, Jean'ne M. .

JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (43) :8232-8238

[25] Dielectric analysis on the phase behavior of ionic liquid-containing nonaqueous microemulsions [J].

Chen, Kai ;

Zhao, Kongshuang .

COLLOID AND POLYMER SCIENCE, 2015, 293 (03) :833-840

[26] Effect of water and ions on the rheological behavior of a low viscosity ammonium-based ionic liquid [J].

Enrique Chavez-Castellanos, Angel ;

Aguilar-Martinez, Martha ;

Manuel Reyna-Gonzalez, Juan .

FLUID PHASE EQUILIBRIA, 2022, 556

[27] Controlled Phase Behavior of Thermally Sensitive Poly(N-isopropylacrylamide/ionic liquid) with Embedded Au Nanoparticles [J].

Gupta, Surabhi ;

Singh, Ankit ;

Matsumi, Noriyoshi .

ACS OMEGA, 2019, 4 (25) :20923-20930

[28] Self-assembly of supramolecular complexes of charged conjugated polymers and imidazolium-based ionic liquid crystals [J].

Zhang, Shanju ;

Beach, Evan ;

Anastas, Paul T. ;

Pfefferle, Lisa D. ;

Osuji, Chinedum O. .

GIANT, 2022, 9

[29] Counterion effect on the phase behavior of perfluoropolyether carboxylates: micelles and liquid crystals in water [J].

Caboi, F ;

Chittofrati, A ;

Lazzari, P ;

Monduzzi, M .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1999, 160 (01) :47-56

[30] Ionic Switch Induced by a Rectangular-Hexagonal Phase Transition in Benzenammonium Columnar Liquid Crystals [J].

Soberats, Bartolome ;

Yoshio, Masafumi ;

Ichikawa, Takahiro ;

Zeng, Xiangbing ;

Ohno, Hiroyuki ;

Ungar, Goran ;

Kato, Takashi .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (41) :13212-13215

← 1 2 3 4 5 →