Interrupted Michael Reaction: Sulfophosphinoylation of α,β-Unsaturated Ketones Catalyzed by Phosphine

被引：1

作者：

Wei, Xiao-Hong ^{[1
]}

Xue, Ya-Wen ^{[1
]}

Liu, Xuan ^{[1
]}

Wang, Xiao-Hong ^{[1
]}

Wang, Yan-Bin ^{[1
]}

Su, Qiong ^{[1
]}

机构：

[1] Northwest Minzu Univ, Coll Chem Engn, Key Lab Environm Friendly Composite Mat, Key Lab Util Environm Friendly Composite Mat & Bio, Lanzhou 730030, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 89卷 / 22期

基金：

中国国家自然科学基金;

关键词：

MORITA-BAYLIS-HILLMAN; 4+1 ANNULATION; C BOND; CARBONATES; OXIDES; CONSTRUCTION; ALLENES; ACCESS; ACID; 3-NITROINDOLES;

D O I：

10.1021/acs.joc.4c01860

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient method for phosphine-catalyzed sulfophosphinoylation of alpha,beta-unsaturated ketones for synthesis allylic organophosphorus compounds has been reported, in which alpha,beta-unsaturated compounds acting as zwitterions react with electrophiles and nucleophiles to form a C-P bond and a C-O bond and obtain allylic organophosphorus with high regio- and stereoselectivity in moderate to excellent yields.

引用

页码：16564 / 16570

页数：7

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