High entropy or combinatorial heterogeneous catalysis?

被引：0

作者：

Ozin, Geoffrey ^{[1
]}

机构：

[1] Univ Toronto, Solar Fuels Grp, Toronto, ON, Canada

来源：

MATTER | 2025年 / 8卷 / 01期

关键词：

D O I：

10.1016/j.matt.2024.11.010

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

While the configurational entropy of a multi-element solid solution material contributes to its thermodynamic stability, by contrast, its performance as a heterogeneous catalyst depends on the kinetics of converting reactants to products. This calls into question whether a kinetic advantage originates in a high-entropy effect or a combinatorial means of optimizing surface chemistry and catalysis.

引用

页数：2

共 10 条

[1] Complex concentrated alloys and chemical short-range ordering [J].

Beyerlein, Irene J. ;

Cao, Penghui ;

Pollock, Tresa M. .

MRS BULLETIN, 2023, 48 (7) :746-752

[2] What is in a name: Defining "high entropy" oxides [J].

Brahlek, Matthew ;

Gazda, Maria ;

Keppens, Veerle ;

Mazza, Alessandro R. ;

McCormack, Scott J. ;

Mielewczyk-Gryn, Aleksandra ;

Musico, Brianna ;

Page, Katharine ;

Rost, Christina M. ;

Sinnott, Susan B. ;

Toher, Cormac ;

Ward, Thomas Z. ;

Yamamoto, Ayako .

APL MATERIALS, 2022, 10 (11)

[3] Combinatorial synthesis for AI-driven materials discovery [J].

Gregoire, John M. ;

Zhou, Lan ;

Haber, Joel A. .

NATURE SYNTHESIS, 2023, 2 (06) :493-504

[4] High-entropy energy materials: challenges and new opportunities [J].

Ma, Yanjiao ;

Ma, Yuan ;

Wang, Qingsong ;

Schweidler, Simon ;

Botros, Miriam ;

Fu, Tongtong ;

Hahn, Horst ;

Brezesinski, Torsten ;

Breitung, Ben .

ENERGY & ENVIRONMENTAL SCIENCE, 2021, 14 (05) :2883-2905

[5] On the deviation from the Vegard's law for the solid solutions [J].

Magomedov, M. N. .

SOLID STATE COMMUNICATIONS, 2020, 322

[6]

Market Research Future, 2024, About Us

[7] Heterogeneous Catalysis [J].

Schloegl, Robert .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (11) :3465-3520

[8] Impact of surface chemistry [J].

Somorjai, Gabor A. ;

Li, Yimin .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2011, 108 (03) :917-924

[9] Heterogeneous partial oxidation catalysis on metal oxides [J].

Vedrine, Jacques C. ;

Fechete, Ioana .

COMPTES RENDUS CHIMIE, 2016, 19 (10) :1203-1225

[10] Bringing down the heat in methanol synthesis [J].

Wang, Andrew ;

Tountas, Athanasios A. ;

Aspuru-Guzik, Alan ;

Ozin, Geoffrey A. .

MATTER, 2023, 6 (07) :2106-2135

← 1 →