Zinc(II) 2D Coordination Polymer With Terephthalate and 4,6-Bis(Imidazol-1-yl)-2,1,3-Benzoxadiazole Linkers as a Selective Luminescent Probe for Gallium(III) Cations

被引：1
作者：
Pavlova, Vladislava V. [1 ,2 ]
Pavlov, Dmitry I. [1 ,2 ]
Ryadun, Alexey A. [2 ]
Sadykov, Evgeny H. [2 ]
Guselnikova, Tatiana Y. [2 ]
Fedin, Vladimir P. [1 ,2 ]
Yu, Xiaolin [2 ,3 ]
Potapov, Andrei S. [1 ,2 ]
机构：
[1] Novosibirsk State Univ, Novosibirsk, Russia
[2] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
[3] Dalian Univ Technol, Sch Chem, Dalian, Peoples R China
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2025年 / 39卷 / 03期
基金：
俄罗斯科学基金会;
关键词：
crystal structure; gallium; luminescence; metal-organic frameworks; sensor; METAL-ORGANIC FRAMEWORKS; STRIPPING VOLTAMMETRY; WATER; COMPLEXES; SPECTROMETRY; ION;
D O I：
10.1002/aoc.70091
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A two-dimensional (2D) zinc(II) coordination polymer CP-1, [Zn(im(2)bod)(bdc)](n) (im(2)bod = 4,6-bis(imidazol-1-yl)-2,1,3-benzoxadiazole, bdc(2)- = 1,4-benzenedicarboxylate), was synthesized and fully characterized. CP-1 crystallizes in the monoclinic crystal system, space group P2(1)/n. Zn2+ ions adopt a four-coordinated distorted tetrahedral geometry. The structure of CP-1 comprises a two-dimensional layer consisting Zn2+ cations connected by im(2)bod and bdc(2-) ligands. The adjutant layers participate in pi-pi stacking interactions via the benzene and 2,1,3-benzoxadiazole rings. CP-1 demonstrated a blue emission with the maximum at 490 nm and a photoluminescence quantum yield 24%. Luminescent sensing properties of CP-1 in aqueous suspension toward metal cations were evaluated, and selective emission quenching response was observed toward Ga3+ cations with the limit of detection 10 mu M.
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页数：10
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