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Ruthenium-Catalyzed Deconstruction of Polyolefins: A Strategy to Up-cycle Waste Polyethylene to Value-Added Alkene
被引:4
作者:

Padhi, Ganeshdev
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CSIR Natl Chem Lab, Organ Chem Div, Dr Homi Bhabha Rd, Pune 411008, India
Acad Sci & Innovat Res AcSIR, Sect 19, Ghaziabad 201002, Uttar Pradesh, India CSIR Natl Chem Lab, Organ Chem Div, Dr Homi Bhabha Rd, Pune 411008, India

Khopade, Kishor V.
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CSIR Natl Chem Lab, Polymer Sci & Engn Div, Dr Homi Bhabha Rd, Pune 411008, India
Acad Sci & Innovat Res AcSIR, Sect 19, Ghaziabad 201002, Uttar Pradesh, India CSIR Natl Chem Lab, Organ Chem Div, Dr Homi Bhabha Rd, Pune 411008, India

Moyilla, Nageswararao
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CSIR Natl Chem Lab, Organ Chem Div, Dr Homi Bhabha Rd, Pune 411008, India CSIR Natl Chem Lab, Organ Chem Div, Dr Homi Bhabha Rd, Pune 411008, India

Rangappa, Raghavendrakumar
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CSIR Natl Chem Lab, Polymer Sci & Engn Div, Dr Homi Bhabha Rd, Pune 411008, India CSIR Natl Chem Lab, Organ Chem Div, Dr Homi Bhabha Rd, Pune 411008, India

Chikkali, Samir H.
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CSIR Natl Chem Lab, Polymer Sci & Engn Div, Dr Homi Bhabha Rd, Pune 411008, India
Acad Sci & Innovat Res AcSIR, Sect 19, Ghaziabad 201002, Uttar Pradesh, India CSIR Natl Chem Lab, Organ Chem Div, Dr Homi Bhabha Rd, Pune 411008, India

Barsu, Nagaraju
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CSIR Natl Chem Lab, Organ Chem Div, Dr Homi Bhabha Rd, Pune 411008, India
Acad Sci & Innovat Res AcSIR, Sect 19, Ghaziabad 201002, Uttar Pradesh, India CSIR Natl Chem Lab, Organ Chem Div, Dr Homi Bhabha Rd, Pune 411008, India
机构:
[1] CSIR Natl Chem Lab, Organ Chem Div, Dr Homi Bhabha Rd, Pune 411008, India
[2] CSIR Natl Chem Lab, Polymer Sci & Engn Div, Dr Homi Bhabha Rd, Pune 411008, India
[3] Acad Sci & Innovat Res AcSIR, Sect 19, Ghaziabad 201002, Uttar Pradesh, India
关键词:
Deconstruction;
Homogeneous catalysis;
Ruthenium;
Upcycling;
Waste plastic;
DEHYDROGENATION;
ISOMERIZATION;
OXIDATION;
LIGANDS;
ALKANES;
D O I:
10.1002/anie.202422609
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Synthesis of value-added products from post-consumer waste polyolefins is fascinating as well as challenging. Here we report ruthenium-catalyzed up-cycling of the polyethylene to long-chain alkene derivatives. The developed methodology mainly involves two steps i.e., dehydrogenation of polyethylene through hydrogen atom transfer and its metathesis using the HG-II catalyst. The dehydrogenation of polyethylene using ruthenium catalysis derived up to 3.38 %, of double bonds; with 90 % of the recovered polyolefin material. The obtained unsaturated polyethylene was subjected to cross-metathesis with ethylene using HG-II catalytic system. This resulted in the synthesis of predominantly dodecene (C12) derivatives, with 58 % selectivity, along with other derivatives of varying chain lengths. The overall reaction produced terminal and internal olefins in the ratio 1:0.8 respectively. The dehydrogenation of polyethylene and its deconstruction was confirmed by NMR spectroscopy, Gel Permeation Chromatography (GPC) and Differential Scanning Calorimetry (DSC). The origin of C12 selectivity has been demonstrated by control experiments. The scope of the methodology was extended to post-consumer waste polyethylene which gave high conversion to value-added dodecene derivatives as a major product.
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共 46 条
[1]
Development of isomerization and cycloisomerization with use of a ruthenium hydride with N-heterocyclic carbene and its application to the synthesis of heterocycles
[J].
Arisawa, Mitsuhiro
;
Terada, Yukiyoshi
;
Takahashi, Kazuyuki
;
Nakagawa, Masako
;
Nishida, Atsushi
.
JOURNAL OF ORGANIC CHEMISTRY,
2006, 71 (11)
:4255-4261

Arisawa, Mitsuhiro
论文数: 0 引用数: 0
h-index: 0
机构:
Chiba Univ, Grad Sch Pharmaceut Sci, Inage Ku, Chiba 2638522, Japan Chiba Univ, Grad Sch Pharmaceut Sci, Inage Ku, Chiba 2638522, Japan

Terada, Yukiyoshi
论文数: 0 引用数: 0
h-index: 0
机构:
Chiba Univ, Grad Sch Pharmaceut Sci, Inage Ku, Chiba 2638522, Japan Chiba Univ, Grad Sch Pharmaceut Sci, Inage Ku, Chiba 2638522, Japan

Takahashi, Kazuyuki
论文数: 0 引用数: 0
h-index: 0
机构:
Chiba Univ, Grad Sch Pharmaceut Sci, Inage Ku, Chiba 2638522, Japan Chiba Univ, Grad Sch Pharmaceut Sci, Inage Ku, Chiba 2638522, Japan

Nakagawa, Masako
论文数: 0 引用数: 0
h-index: 0
机构:
Chiba Univ, Grad Sch Pharmaceut Sci, Inage Ku, Chiba 2638522, Japan Chiba Univ, Grad Sch Pharmaceut Sci, Inage Ku, Chiba 2638522, Japan

Nishida, Atsushi
论文数: 0 引用数: 0
h-index: 0
机构:
Chiba Univ, Grad Sch Pharmaceut Sci, Inage Ku, Chiba 2638522, Japan Chiba Univ, Grad Sch Pharmaceut Sci, Inage Ku, Chiba 2638522, Japan
[2]
Catalytic Chemical Recycling of Post-Consumer Polyethylene
[J].
Arroyave, Alejandra
;
Cui, Shilin
;
Lopez, Jaqueline C.
;
Kocen, Andrew L.
;
LaPointe, Anne M.
;
Delferro, Massimiliano
;
Coates, Geoffrey W.
.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
2022, 144 (51)
:23280-23285

Arroyave, Alejandra
论文数: 0 引用数: 0
h-index: 0
机构:
Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA

Cui, Shilin
论文数: 0 引用数: 0
h-index: 0
机构:
Cornell Univ, Dept Chem & Chem Biol, Baker Lab, Ithaca, NY 14853 USA Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA

Lopez, Jaqueline C.
论文数: 0 引用数: 0
h-index: 0
机构:
Cornell Univ, Dept Chem & Chem Biol, Baker Lab, Ithaca, NY 14853 USA Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA

Kocen, Andrew L.
论文数: 0 引用数: 0
h-index: 0
机构:
Cornell Univ, Dept Chem & Chem Biol, Baker Lab, Ithaca, NY 14853 USA Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA

LaPointe, Anne M.
论文数: 0 引用数: 0
h-index: 0
机构:
Cornell Univ, Dept Chem & Chem Biol, Baker Lab, Ithaca, NY 14853 USA Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA

Delferro, Massimiliano
论文数: 0 引用数: 0
h-index: 0
机构:
Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA
Univ Chicago, Pritzker Sch Mol Engn, Chicago, IL 60637 USA Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA

Coates, Geoffrey W.
论文数: 0 引用数: 0
h-index: 0
机构:
Cornell Univ, Dept Chem & Chem Biol, Baker Lab, Ithaca, NY 14853 USA Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA
[3]
Ruthenium complexes with non-innocent ligands: Electron distribution and implications for catalysis
[J].
Boyer, Julie L.
;
Rochford, Jonathan
;
Tsai, Ming-Kang
;
Muckerman, James T.
;
Fujita, Etsuko
.
COORDINATION CHEMISTRY REVIEWS,
2010, 254 (3-4)
:309-330

Boyer, Julie L.
论文数: 0 引用数: 0
h-index: 0
机构:
Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

Rochford, Jonathan
论文数: 0 引用数: 0
h-index: 0
机构:
Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

Tsai, Ming-Kang
论文数: 0 引用数: 0
h-index: 0
机构:
Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

Muckerman, James T.
论文数: 0 引用数: 0
h-index: 0
机构:
Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

Fujita, Etsuko
论文数: 0 引用数: 0
h-index: 0
机构:
Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA
[4]
Plastic rain in protected areas of the United States
[J].
Brahney, Janice
;
Hallerud, Margaret
;
Heim, Eric
;
Hahnenberger, Maura
;
Sukumaran, Suja
.
SCIENCE,
2020, 368 (6496)
:1257-+

论文数: 引用数:
h-index:
机构:

论文数: 引用数:
h-index:
机构:

论文数: 引用数:
h-index:
机构:

Hahnenberger, Maura
论文数: 0 引用数: 0
h-index: 0
机构:
Salt Lake Community Coll, Geosci Dept, Salt Lake City, UT 84123 USA Utah State Univ, Dept Watershed Sci, Logan, UT 84322 USA

Sukumaran, Suja
论文数: 0 引用数: 0
h-index: 0
机构:
Thermo Fisher Sci, Mat & Struct Anal Div, San Jose, CA 95134 USA Utah State Univ, Dept Watershed Sci, Logan, UT 84322 USA
[5]
New avenues for ligand-mediated processes - expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands
[J].
Broere, Daniel L. J.
;
Plessius, Raoul
;
van der Vlugt, Jarl Ivar
.
CHEMICAL SOCIETY REVIEWS,
2015, 44 (19)
:6886-6915

Broere, Daniel L. J.
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Amsterdam, vant Hoff Inst Mol Sci, Homogeneous Bioinspired & Supramol Catalysis Grp, Amsterdam, Netherlands Univ Amsterdam, vant Hoff Inst Mol Sci, Homogeneous Bioinspired & Supramol Catalysis Grp, Amsterdam, Netherlands

Plessius, Raoul
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Amsterdam, vant Hoff Inst Mol Sci, Homogeneous Bioinspired & Supramol Catalysis Grp, Amsterdam, Netherlands Univ Amsterdam, vant Hoff Inst Mol Sci, Homogeneous Bioinspired & Supramol Catalysis Grp, Amsterdam, Netherlands

van der Vlugt, Jarl Ivar
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Amsterdam, vant Hoff Inst Mol Sci, Supramol Homogeneous Catalysis Grp, Amsterdam, Netherlands Univ Amsterdam, vant Hoff Inst Mol Sci, Homogeneous Bioinspired & Supramol Catalysis Grp, Amsterdam, Netherlands
[6]
Preface: Forum on Redox-Active Ligands
[J].
Chirik, Paul J.
.
INORGANIC CHEMISTRY,
2011, 50 (20)
:9737-9740

Chirik, Paul J.
论文数: 0 引用数: 0
h-index: 0
机构:
Princeton Univ, Dept Chem, Princeton, NJ 08544 USA Princeton Univ, Dept Chem, Princeton, NJ 08544 USA
[7]
General, Mild, and Selective Method for Desaturation of Aliphatic Amines
[J].
Chuentragool, Padon
;
Parasram, Marvin
;
Shi, Yi
;
Gevorgyan, Vladimir
.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
2018, 140 (07)
:2465-2468

Chuentragool, Padon
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Illinois, Dept Chem, 845 West Taylor St, Chicago, IL 60607 USA Univ Illinois, Dept Chem, 845 West Taylor St, Chicago, IL 60607 USA

Parasram, Marvin
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Illinois, Dept Chem, 845 West Taylor St, Chicago, IL 60607 USA Univ Illinois, Dept Chem, 845 West Taylor St, Chicago, IL 60607 USA

Shi, Yi
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Illinois, Dept Chem, 845 West Taylor St, Chicago, IL 60607 USA Univ Illinois, Dept Chem, 845 West Taylor St, Chicago, IL 60607 USA

Gevorgyan, Vladimir
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Illinois, Dept Chem, 845 West Taylor St, Chicago, IL 60607 USA Univ Illinois, Dept Chem, 845 West Taylor St, Chicago, IL 60607 USA
[8]
Catalytic deconstruction of waste polyethylene with ethylene to form propylene
[J].
Conk, Richard J.
;
Hanna, Steven
;
Shi, Jake X.
;
Yang, Ji
;
Ciccia, Nicodemo R.
;
Qi, Liang
;
Bloomer, Brandon J.
;
Heuvel, Steffen
;
Wills, Tyler
;
Su, Ji
;
Bell, Alexis T.
;
Hartwig, John F.
.
SCIENCE,
2022, 377 (6614)
:1561-+

Conk, Richard J.
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

Hanna, Steven
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

Shi, Jake X.
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

Yang, Ji
论文数: 0 引用数: 0
h-index: 0
机构:
Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

Ciccia, Nicodemo R.
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

Qi, Liang
论文数: 0 引用数: 0
h-index: 0
机构:
Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA
Univ Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94720 USA Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

Bloomer, Brandon J.
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

Heuvel, Steffen
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

Wills, Tyler
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

Su, Ji
论文数: 0 引用数: 0
h-index: 0
机构:
Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

Bell, Alexis T.
论文数: 0 引用数: 0
h-index: 0
机构:
Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA
Univ Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94720 USA Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

Hartwig, John F.
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[9]
Heterogeneous Pt-catalyzed transfer dehydrogenation of long-chain alkanes with ethylene
[J].
de la Croix, Tim
;
Claes, Nathalie
;
Eyley, Samuel
;
Thielemans, Wim
;
Bals, Sara
;
De Vos, Dirk
.
CATALYSIS SCIENCE & TECHNOLOGY,
2023, 13 (24)
:7123-7135

de la Croix, Tim
论文数: 0 引用数: 0
h-index: 0
机构:
Katholieke Univ Leuven, Ctr Membrane Separat Adsorpt Catalysis & Spect Sus, Dept Microbial & Mol Syst, B-3001 Leuven, Belgium Katholieke Univ Leuven, Ctr Membrane Separat Adsorpt Catalysis & Spect Sus, Dept Microbial & Mol Syst, B-3001 Leuven, Belgium

论文数: 引用数:
h-index:
机构:

Eyley, Samuel
论文数: 0 引用数: 0
h-index: 0
机构:
Katholieke Univ Leuven, Dept Chem Engn, Sustainable Mat Lab, Campus Kulak Kortrijk, B-8500 Kortrijk, Belgium Katholieke Univ Leuven, Ctr Membrane Separat Adsorpt Catalysis & Spect Sus, Dept Microbial & Mol Syst, B-3001 Leuven, Belgium

Thielemans, Wim
论文数: 0 引用数: 0
h-index: 0
机构:
Katholieke Univ Leuven, Dept Chem Engn, Sustainable Mat Lab, Campus Kulak Kortrijk, B-8500 Kortrijk, Belgium Katholieke Univ Leuven, Ctr Membrane Separat Adsorpt Catalysis & Spect Sus, Dept Microbial & Mol Syst, B-3001 Leuven, Belgium

论文数: 引用数:
h-index:
机构:

De Vos, Dirk
论文数: 0 引用数: 0
h-index: 0
机构:
Katholieke Univ Leuven, Ctr Membrane Separat Adsorpt Catalysis & Spect Sus, Dept Microbial & Mol Syst, B-3001 Leuven, Belgium Katholieke Univ Leuven, Ctr Membrane Separat Adsorpt Catalysis & Spect Sus, Dept Microbial & Mol Syst, B-3001 Leuven, Belgium
[10]
Tandem Heterogeneous Catalysis for Polyethylene Depolymerization via an Olefin-Intermediate Process
[J].
Ellis, Lucas D.
;
Orski, Sara, V
;
Kenlaw, Grace A.
;
Norman, Andrew G.
;
Beers, Kathryn L.
;
Roman-Leshkov, Yuriy
;
Beckham, Gregg T.
.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING,
2021, 9 (02)
:623-628

Ellis, Lucas D.
论文数: 0 引用数: 0
h-index: 0
机构:
Natl Renewable Energy Lab, Renewable Resources & Enabling Sci Ctr, Golden, CO 80401 USA Natl Renewable Energy Lab, Renewable Resources & Enabling Sci Ctr, Golden, CO 80401 USA

Orski, Sara, V
论文数: 0 引用数: 0
h-index: 0
机构:
NIST, Mat Sci & Engn Div, Gaithersburg, MD 20899 USA Natl Renewable Energy Lab, Renewable Resources & Enabling Sci Ctr, Golden, CO 80401 USA

Kenlaw, Grace A.
论文数: 0 引用数: 0
h-index: 0
机构:
NIST, Mat Sci & Engn Div, Gaithersburg, MD 20899 USA Natl Renewable Energy Lab, Renewable Resources & Enabling Sci Ctr, Golden, CO 80401 USA

Norman, Andrew G.
论文数: 0 引用数: 0
h-index: 0
机构:
Natl Renewable Energy Lab, Mat Sci Ctr, Golden, CO 80401 USA Natl Renewable Energy Lab, Renewable Resources & Enabling Sci Ctr, Golden, CO 80401 USA

Beers, Kathryn L.
论文数: 0 引用数: 0
h-index: 0
机构:
NIST, Mat Sci & Engn Div, Gaithersburg, MD 20899 USA Natl Renewable Energy Lab, Renewable Resources & Enabling Sci Ctr, Golden, CO 80401 USA

Roman-Leshkov, Yuriy
论文数: 0 引用数: 0
h-index: 0
机构:
MIT, Dept Chem Engn, Cambridge, MA 02139 USA Natl Renewable Energy Lab, Renewable Resources & Enabling Sci Ctr, Golden, CO 80401 USA

Beckham, Gregg T.
论文数: 0 引用数: 0
h-index: 0
机构:
Natl Renewable Energy Lab, Renewable Resources & Enabling Sci Ctr, Golden, CO 80401 USA Natl Renewable Energy Lab, Renewable Resources & Enabling Sci Ctr, Golden, CO 80401 USA