Spin state of manganese ions in double manganite Nd0.9Sm0.1BaMn2O6 by X-ray photoemission and X-ray emission spectroscopy

被引：0
|
作者：
Kantur, Ilia [1 ]
Yarmoshenko, Yuri [1 ]
Radzivonchik, Danil [1 ]
Titova, Svetlana [2 ]
Sterkhov, Eugenii [2 ]
Chumakov, Ratibor [3 ]
Beliaev, Danil [1 ]
Kuznetsova, Tatyana [1 ,4 ]
机构：
[1] Russian Acad Sci, MN Mikheev Inst Met Phys, Ural Branch, Ekaterinburg 620108, Russia
[2] Russian Acad Sci, Inst Met, Ural Branch, Ekaterinburg 620016, Russia
[3] Natl Res Ctr, Kurchatov Inst, Moscow 123182, Russia
[4] Eltsin Ural Fed Univ, Ekaterinburg 620002, Russia
来源：
MATERIALS LETTERS | 2025年 / 382卷
基金：
俄罗斯科学基金会;
关键词：
XES; XPS; Double manganites; Spin state; SPECTRA;
D O I：
10.1016/j.matlet.2024.137850
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
In this paper, Mn 2p, Nd 3d and 4d core levels in Nd0.9Sm0.1BaMn2O6 were studied by X-ray photoelectron spectroscopy (XPS) and X-ray emission spectroscopy (XES). The obtained photoelectron spectra of Mn demonstrate the presence of Mn in oxidation states 3+ and 4+. From the shape of the XES spectrum of the K(3 line of manganese and the presence of the satellite K(3' at energy E = 6476 eV, the spin state of the manganese ion in the compound can be determined. The experimental emission spectra of Mn are compared with the multiplet calculation. The analysis of XPS spectra of the double manganite Nd0.9Sm0.1BaMn2O6 compound shows 3+ and 4+ oxidation states of Mn ions with 2:1 ratio, respectively. The analysis of Mn K(3 XES spectrum of the Nd0.9Sm0.1BaMn2O6 based on multiplet calculations shows the Mn3+/Mn4+ ion ratio to be 1:1, which is often typical for the RBaMn2O6 compounds. The calculation also reveals the high-spin state of Mn3+.
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页数：4
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