Structural analysis of isolated components in microalgal lipids: Neutral lipids, phospholipids, and glycolipids

被引:1
作者
Qiu, Huiyu [1 ]
Wang, Yi [1 ]
Zuo, Menghao [1 ]
Wang, Xin [1 ]
Shen, Boxiong [2 ,3 ]
机构
[1] Hebei Univ Technol, Sch Energy & Environm Engn, Tianjin Key Lab Clean Energy & Pollut Control, Tianjin, Peoples R China
[2] Hebei Univ Technol, Sch Chem Engn, Tianjin, Peoples R China
[3] Hebei Engn Res Ctr Pollut Control Power Syst, Tianjin 300401, Peoples R China
基金
中国国家自然科学基金;
关键词
Microalgae; Lipids; Neutral lipids; Phospholipids; Glycolipids; Cracking pathway; PERFORMANCE LIQUID-CHROMATOGRAPHY; FATTY-ACID-COMPOSITION; PLANT OILS; MASS; GLYCOSPHINGOLIPIDS; QUANTIFICATION; MACROALGAE; LIPIDOMICS;
D O I
10.1016/j.biteb.2025.102083
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
Microalgal lipids are important feedstock for alternative liquid biofuels. The composition and molecular structure of lipids affect physicochemical properties of obtained liquid biofuels and rational design of composite catalysts during catalytic conversion. However, there is still short of detailed information on composition of microalgal lipids. In this study, neutral lipids, phospholipids, and glycolipids were isolated and analyzed via ultra-high performance chromatography and high-resolution mass spectrometry. A total of twenty-five compounds had been identified via the special information of the mass-to-charge ratio m/z, including fifteen kinds of neutral lipids, four kinds of phospholipids, three kinds of glycolipids, and three kinds of sphingolipids. The main cracking mechanism of these compounds during pyrolysis were cracking of fatty acid chains (C16, C18, and C20) from backbone of glycerol, forming different distributions of low molecular species. Monosaccharide such as glucose, amide group, and phosphate group were also typical structures in microalgal lipids.
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页数:8
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