Gold(I)-Catalyzed Intramolecular C(sp3)-H Bond Functionalization

被引：0
作者：
Miguelez, Ruben
Arto, Omar
Rodriguez-Arias, Carlos
Barrio, Pablo [1 ]
机构：
[1] Univ Oviedo, Dept Quim Organ & Inorgan, Ave Julian Claveria 8, Oviedo 33006, Spain
来源：
SYNTHESIS-STUTTGART | 2025年 / 57卷 / 06期
关键词：
gold-catalysis; C-H functionalization; cyclization; carbene insertion; 1,5]-hydride shift; vinyl cation; C-H BOND; GOLD-CATALYZED SYNTHESIS; RETRO-BUCHNER REACTION; UNACTIVATED C(SP(3))-H BONDS; ASYMMETRIC ALDOL REACTION; SUBSTITUTED ARYL ALKYNES; FACE-SELECTIVE PLATINUM; INSERTION REACTIONS; STEREOSELECTIVE CONSTRUCTION; CYCLOISOMERIZATION REACTIONS;
D O I：
10.1055/a-2389-7434
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The merger of two of the most rapidly growing fields in catalysis, namely gold-catalysis and C-H activation/functionalization has resulted in major breakthroughs, affording unprecedented transformations. This review covers the most relevant contributions in this field during the last 10 years, restricted to the intramolecular functionalization of C(sp(3))-H bonds.
引用
收藏
页码：1138 / 1152
页数：15
相关论文
共 259 条
[1]   Carboxylate-Assisted Transition-Metal-Catalyzed C-H Bond Functionalizations: Mechanism and Scope [J].
Ackermann, Lutz .
CHEMICAL REVIEWS, 2011, 111 (03) :1315-1345
[2]   Divergent C-H Insertion-Cyclization Cascades of N-Allyl Ynamides [J].
Adcock, Holly V. ;
Chatzopoulou, Elli ;
Davies, Paul W. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (51) :15525-15529
[3]   Gold-catalyzed heterocyclic syntheses through α-imino gold carbene complexes as intermediates Dedicated to Professor Dr Julius Rebek, Jr. on the occasion of his 75th birthday. [J].
Aguilar, Enrique ;
Santamaria, Javier .
ORGANIC CHEMISTRY FRONTIERS, 2019, 6 (09) :1513-1540
[4]   Synthesis of Fulvene Vinyl Ethers by Gold Catalysis [J].
Ahrens, Alexander ;
Schwarz, Julia ;
Lustosa, Danilo M. ;
Pourkaveh, Raheleh ;
Hoffmann, Marvin ;
Rominger, Frank ;
Rudolph, Matthias ;
Dreuw, Andreas ;
Hashmi, A. Stephen K. .
CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (23) :5280-5287
[5]   Oxidant-free oxidative gold catalysis: the new paradigm in cross-coupling reactions [J].
Akram, Manjur O. ;
Banerjee, Somsuvra ;
Saswade, Sagar S. ;
Bedi, Vaibhav ;
Patil, Nitin T. .
CHEMICAL COMMUNICATIONS, 2018, 54 (79) :11069-11083
[6]   Gold(I)-Catalyzed Indole Synthesis through Aza-Nazarov-Type Cyclization of α-Imino Gold Carbene Complexes and Arenes [J].
Allegue, Dario ;
Santamaria, Javier ;
Ballesteros, Alfredo .
ADVANCED SYNTHESIS & CATALYSIS, 2021, 363 (23) :5272-5278
[7]   Regiodivergent Control in the Gold(I) Catalyzed Synthesis of 7-Pyrazolylindoles from 1-Propargyl-1H-benzotriazoles and Ynamides through α-Imino Gold(I) Carbene Complexes [J].
Allegue, Dario ;
Gonzalez, Jairo ;
Fernandez, Sergio ;
Santamaria, Javier ;
Ballesteros, Alfredo .
ADVANCED SYNTHESIS & CATALYSIS, 2019, 361 (04) :758-768
[8]   Gold-based enantioselective bimetallic catalysis [J].
Ambegave, Shivhar B. B. ;
Shubham ;
More, Tushar R. R. ;
Patil, Nitin T. T. .
CHEMICAL COMMUNICATIONS, 2023, 59 (52) :8007-8016
[9]   BNC ISOSTERES OF CYCLOPROPANE AND A BORYLATED DIAZOESTER FROM DIAZO-COMPOUNDS AND (DIMETHYLAMINO)BIS(TRIFLUOROMETHYL)BORANE [J].
ANSORGE, A ;
BRAUER, DJ ;
BURGER, H ;
HAGEN, T ;
PAWELKE, G .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (03) :384-385
[10]   SYNTHESIS OF THE 1ST DISTILLABLE ALPHA-BORANYLDIAZOMETHANE - DIRECT EVIDENCE OF LITHIOBORANYLDIAZOMETHANE-LITHIOBORANYLISODIAZO-METHANE [(BCNN-,LI+)-(BNNC-,LI+)] REARRANGEMENT [J].
ARTHUR, MP ;
BACEIREDO, A ;
BERTRAND, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (15) :5856-5857
12345678910