Investigating electrical conductivity and antimicrobial performance of niobium oxide and praseodymium oxide nanoparticles filled Chitosan-PVA polymer blends

被引:0
作者
Alharbi, Khadijah H. [1 ,2 ]
Alharbi, Walaa [1 ,2 ]
Almuslem, Amani Saleh [3 ]
El-Morsy, M. A. [4 ,5 ]
Farea, M. O. [6 ]
机构
[1] King Abdulaziz Univ, Dept Chem Sci, Rabigh, Saudi Arabia
[2] King Abdulaziz Univ, Arts Coll, Rabigh, Saudi Arabia
[3] King Faisal Univ, Coll Sci, Dept Phys, Al Hasa 31982, Saudi Arabia
[4] Prince Sattam Bin Abdulaziz Univ, Coll Sci & Humanities Al Kharj, Phys Dept, Plasma Technol & Mat Sci Unit, Al Kharj 11942, Saudi Arabia
[5] Univ Damietta, Fac Sci, Phys Dept, Dumyat 34517, Egypt
[6] Mansoura Univ, Fac Sci, Dept Phys, Mansoura 35516, Egypt
关键词
Chitosan; PVA; Dielectric; TGA; Optical; Antimicrobial activity; ANTIBACTERIAL ACTIVITY; NB2O5;
D O I
10.1016/j.inoche.2025.113994
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Energy storage has shown interest in CS-PVA-based composites due to their antibacterial and biocompatible characteristics. For biological research, chitosan (CS)-polyvinyl alcohol (PVA) doped with Nb2O5-Pr6O11 composites are being investigated. The structural study is verified by FT-IR/XRD/EDX/XPS analysis. SEM measurement shows that the size of Nb2P5 rods ranges between 0.5 and 0.8 mu m. The effect of Oxy-dopants variation on the optical characterization of CS-PVA-based composites was examined. All samples exhibit high stability until 400 degrees C which is detected through thermal analysis. The largest indirect band gap is also found in pure CSPVA, and it decreases with oxy-dopants and hits 2.95 eV for CS-PVA-Nb2O5-10 % Pr6O11. Furthermore, the decrease in the band gap is consistent with the data from the XRD investigation and indicates enhanced crystalline ordering. The refractive index also decreases upon adding dopants to reach a value of 2.2 at CS-PVANb2O5-10 % Pr6O11. Plots of 8' and 8" show a diminishing trend as frequency increases, with constant values at higher frequencies. Introduced as the antibacterial activity that is most effective against S. aureus and E. coli is the CS-PVA-Nb2O5-30 %Pr6O11 with values of 14.3 +/- 0.2 and 16 +/- 0.3 mm respectively. All of the aforementioned arguments suggest the utilization of CS-PVA-based composites in electrical and biological applications.
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页数:11
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