Electrochemical Hydrogen Evolution with Metal-Organic Framework-Derived Catalysts: Strategies for d-Band Modulation by Electronic Structure Modification

The effective use of metal-organic framework (MOF)-based materials in the electrocatalytic hydrogen evolution reaction (HER) relies on the understanding of their structural and electronic properties. While the structure and morphology of MOF-derived catalysts significantly impact HER activity, tuning the d-band structure through electronic structure modulation has emerged as a key factor in optimizing catalytic performance. Techniques such as composition tuning, heteroatom doping, surface modification, and interface engineering were found to be effective methods for manipulating the electronic configuration and, in turn, modulating the d-band. This review systematically explores the design strategies for MOF-derived catalysts by focusing on electronic structure modulation. It provides a detailed discussion of the various methods - used to modulate the electronic structure. Furthermore, the review establishes the relationship between d-band tuning, Gibbs free energy, and electronic structure modulation, supported by both spectroscopic and theoretical evidences.