Alkali-Mediated/Catalyzed Transition-Metal-Free Tandem Reaction Triggered by the Borrowing Hydrogen and Aerobic Dehydrogenation Processes of Alcohols

被引：0
|
作者：
Chang, Ai [1 ]
Zhou, Weihao [1 ]
Zhao, Sicong [1 ]
Song, Haowen [1 ]
Zhuang, Yi [1 ]
Lin, Yamei [2 ,3 ]
Huang, Shenlin [2 ]
Lu, Guo-Ping [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Sch Chem & Chem Engn, Nanjing 210094, Peoples R China
[2] Nanjing Forestry Univ, Int Innovat Ctr Forest Chem & Mat, Nanjing 210037, Peoples R China
[3] Nanjing Normal Univ, Sch Food Sci & Pharmaceut Engn, Wenyuanst 200, Nanjing 210032, Peoples R China
来源：
CHEMISTRYSELECT | 2024年 / 9卷 / 40期
关键词：
Aerobic dehydrogenation; Alcohol; Alkali catalysis; Borrowing hydrogen; Tandem reaction; DEHYDRATIVE N-ALKYLATION; ALPHA-ALKYLATION; CATALYST; AMINES; EFFICIENT; KETONES; OXIDATION; INDOLES; GREEN;
D O I：
10.1002/slct.202403630
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The transformation of alcohols to important classes of compounds is a central topic in chemistry because they are abundant, renewable, and attractive building blocks. The alkali-mediated/catalyzed borrowing hydrogen and aerobic dehydrogenation processes of alcohols open a new and sustainable access for the alcohol conversion under transition-metal-free conditions. In this review, we summarize the recent alkali-mediated/catalyzed sequential reactions involving the borrowing hydrogen and aerobic dehydrogenation processes of alcohols. Furthermore, this review not only introduces the tentative pathways of these transformations, but also discusses the role of alkali, solvent effects, and substrate reactivity on these reactions.
引用
收藏
页数：21
相关论文
共 50 条
  • [21] Transition-Metal-Free Synthesis of 3-Acyl Chromones by the Tandem Reaction of Ynones and Methyl Salicylates
    Ye, Ya-Fang
    Li, Feng
    Chen, Jia-Le
    An, Zi-Qian
    Zhang, Gui-Ying
    Wang, Yan-Bo
    JOURNAL OF ORGANIC CHEMISTRY, 2022, 87 (21): : 14005 - 14015
  • [22] Efficient Synthesis of Quinazolinones by Transition-Metal-Free Direct Aerobic Oxidative Cascade Annulation of Alcohols with o-Aminoarylnitriles
    Wang, Qi
    Lv, Miao
    Liu, Jianping
    Li, Yang
    Xu, Qing
    Zhang, Xu
    Cao, Hongen
    CHEMSUSCHEM, 2019, 12 (13) : 3043 - 3048
  • [23] Lithium tert-butoxide mediated α-alkylation of ketones with primary alcohols under transition-metal-free conditions
    Liang, Yu-Feng
    Zhou, Xin-Feng
    Tang, Shi-Ya
    Huang, Yao-Bing
    Feng, Yi-Si
    Xu, Hua-Jian
    RSC ADVANCES, 2013, 3 (21) : 7739 - 7742
  • [24] Aerobic Transition-Metal-Free Visible-Light Photoredox Indole C-3 Formylation Reaction
    Li, Xiang
    Gu, Xiangyong
    Li, Yongjuan
    Li, Pixu
    ACS CATALYSIS, 2014, 4 (06): : 1897 - 1900
  • [25] Transition-Metal-Free, Bronsted Acid-Mediated Cascade Sequence in the Reaction of Propargyl Alcohols with Sulfonamido-indoles/- indolines: Highly Substituted δ- and α-Carbolines
    Selvaraj, Karuppu
    Swamy, K. C. Kumara
    JOURNAL OF ORGANIC CHEMISTRY, 2018, 83 (24): : 15043 - 15056
  • [26] Transition-Metal-Free Transfer Hydrogenative Cascade Reaction of Nitroarenes with Amines/Alcohols: Redox-Economical Access to Benzimidazoles
    Kabi, Arup K.
    Gujjarappa, Raghuram
    Roy, Anupam
    Sahoo, Abhishek
    Musib, Dulal
    Vodnala, Nagaraju
    Singh, Virender
    Malakar, Chandi C.
    JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (21): : 14597 - 14607
  • [27] Molecular iodine mediated transition-metal-free oxidative dehydrogenation of 4,7-dihydropyrazolo[3,4-b]pyridines
    Aggarwal, Ranjana
    Singh, Gulshan
    Kumar, Suresh
    SYNTHETIC COMMUNICATIONS, 2021, 51 (23) : 3601 - 3609
  • [28] Metal-Free Synthesis of Alkenylazaarenes and 2-Aminoquinolines through Base-Mediated Aerobic Oxidative Dehydrogenation of Benzyl Alcohols
    Dahatonde, Dipak J.
    Ghosh, Aritra
    Batra, Sanjay
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2021, 2021 (19) : 2746 - 2751
  • [29] Potassium carbonate-mediated tandem C-S and C-N coupling reaction for the synthesis of phenothiazines under transition-metal-free and ligand-free conditions
    Wu, San
    Hu, Wei-Ye
    Zhang, Song-Lin
    RSC ADVANCES, 2016, 6 (29): : 24257 - 24260
  • [30] Transition-metal-free NaI-mediated reaction of aryl sulfonyl chloride with alkynes: Synthesis of (E)-β-iodovinyl sulfones
    Chen, Dan
    Lin, Li
    Peng, Xiaoyan
    Yu, Xinyi
    Yang, Zhonglie
    Liu, Yutong
    Zhang, Xiaobin
    Li, Jiahong
    Jiang, Hezhong
    TETRAHEDRON LETTERS, 2021, 75
12345