In Situ Construction of Bi12O17Cl2/Bi2S3 S-Scheme Heterojunctions with Enriched Oxygen Vacancies to Enhance Photocatalytic Activity

被引：0

作者：

Guo, Biao ^{[1
]}

Wang, Xianyu ^{[1
]}

Wu, Xia ^{[1
]}

Sun, Xinying ^{[1
]}

Li, Xinyuan ^{[1
]}

Liu, Xinxin ^{[1
]}

Zhou, Lijing ^{[1
]}

Zhao, Zhen ^{[1
,2
]}

机构：

[1] Shenyang Normal Univ, Inst Catalysis Energy & Environm, Coll Chem & Chem Engn, Shenyang 110034, Peoples R China

[2] China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2025年 / 64卷 / 07期

基金：

中国国家自然科学基金;

关键词：

BIVO4-AT-BI2S3; HETEROJUNCTION; BISPHENOL-A; REDUCTION; CR(VI); RICH; DEGRADATION; HETEROSTRUCTURES; PERFORMANCE; FABRICATION; EFFICIENCY;

D O I：

10.1021/acs.iecr.4c04683

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The construction of S-scheme heterojunctions with oxygen vacancies (OVs) is an effective strategy to enhance the photocatalytic activity. In this pioneering study, we successfully fabricated Bi12O17Cl2/Bi2S3 S-scheme heterojunctions with abundant OVs (ROV-BOC/BS) using an anion exchange method. The in situ growth of Bi2S3 (BS) nanorods on OVs-rich Bi12O17Cl2 (ROV-BOC) nanosheets resulted in an interconnected reticulated structure. This structure not only increased the specific surface area of the composite but also established a tightly bound heterojunction, further enhancing the OVs content in the composites. The OVs-induced defect levels provide additional channels for photogenerated charge migration. The synergy between the heterojunction and OVs improved the light absorption and carrier separation efficiency. Consequently, the optimized ROV-BOC/BS-0.1 achieved 95.52% Cr(VI) removal efficiency within 120 min, with apparent reaction rate constants 5.39 and 23.86 times higher than those of pure ROV-BOC and BS, respectively. This investigation provides crucial guidance for designing novel S-scheme heterojunction photocatalysts with abundant OVs.

引用

页码：3841 / 3855

页数：15

共 72 条

[21] S-Scheme photocatalyst TaON/Bi2WO6 nanofibers with oxygen vacancies for efficient abatement of antibiotics and Cr(VI): Intermediate eco-toxicity analysis and mechanistic insights [J].

Li, Shijie ;

Cai, Mingjie ;

Liu, Yanping ;

Wang, Chunchun ;

Lv, Kangle ;

Chen, Xiaobo .

CHINESE JOURNAL OF CATALYSIS, 2022, 43 (10) :2652-2664

[22] Rationally designed Ta3N5/BiOCl S-scheme heterojunction with oxygen vacancies for elimination of tetracycline antibiotic and Cr(VI): Performance, toxicity evaluation and mechanism insight [J].

Li, Shijie ;

Cai, Mingjie ;

Wang, Chunchun ;

Liu, Yanping ;

Li, Neng ;

Zhang, Peng ;

Li, Xin .

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2022, 123 :177-190

[23] Double-defect-induced polarization enhanced OV-BiOBr/Cu2-xS high-low junction for boosted photoelectrochemical hydrogen evolution [J].

Li, Xibao ;

Liu, Qiang ;

Deng, Fang ;

Huang, Juntong ;

Han, Lu ;

He, Chaozheng ;

Chen, Zhi ;

Luo, Yidan ;

Zhu, Yongfa .

APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY, 2022, 314

[24] Engineering BiVO4@Bi2S3 heterojunction by cosharing bismuth atoms toward boosted photocatalytic Cr(VI) reduction [J].

Lian, Xinyi ;

Zhang, Jiguang ;

Zhan, Yue ;

Zhang, Yanping ;

Yang, Shuangli ;

Chen, Zhou ;

Dong, Yunyun ;

Fang, Weiping ;

Yi, Xiaodong .

JOURNAL OF HAZARDOUS MATERIALS, 2021, 406

[25] Structuring dual Z-scheme heterojunction and boosting surface reaction by bifunctional NiCoP modified TiO2/g-C3N4 for improving the photocatalytic activity [J].

Liu, Xinxin ;

Ma, Linyushan ;

Wang, Xianyu ;

Wu, Xia ;

Guo, Biao ;

Zhou, Lijing ;

Zha, Zhen .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 62 :127-139

[26] Boosted Charge Transfer for Highly Efficient Photosynthesis of H2O2 over Z-Scheme I-/K+ Co-Doped g-C3N4/Metal-Organic-Frameworks in Pure Water under Visible Light [J].

Lu, Xize ;

Chen, Zongwei ;

Hu, Zhuofeng ;

Liu, Fuyu ;

Zuo, Zhihong ;

Gao, Zixiang ;

Zhang, Haiguang ;

Zhu, Youcai ;

Liu, Runzeng ;

Yin, Yongguang ;

Cai, Yong ;

Ma, Dongling ;

Zhang, Qingzhe .

ADVANCED ENERGY MATERIALS, 2024, 14 (38)

[27] 2D layered MoS2 loaded on Bi12O17Cl2 nanosheets: An effective visible-light photocatalyst [J].

Ma, Jinying ;

Shi, Lei ;

Wang, Zhimeng ;

Ren, Tieqiang ;

Geng, Zhongxing ;

Qi, Wei .

CERAMICS INTERNATIONAL, 2020, 46 (06) :7438-7445

[28] A facile reflux method for in situ fabrication of a non-cytotoxic Bi2S3/β-Bi2O3/ZnIn2S4 ternary photocatalyst: a novel dual Z-scheme system with enhanced multifunctional photocatalytic activity [J].

Majhi, Dibyananda ;

Das, Krishnendu ;

Bariki, Ranjit ;

Padhan, Subash ;

Mishra, Abtar ;

Dhiman, Rohan ;

Dash, Priyanka ;

Nayak, Bismita ;

Mishra, B. G. .

JOURNAL OF MATERIALS CHEMISTRY A, 2020, 8 (41) :21729-21743

[29] One pot synthesis of CdS/BiOBr/Bi2O2CO3: A novel ternary double Z-scheme heterostructure photocatalyst for efficient degradation of atrazine [J].

Majhi, Dibyananda ;

Das, Krishnendu ;

Mishra, Abtar ;

Dhiman, Rohan ;

Mishra, B. G. .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2020, 260

[30] BiOBr/Bi2S3 heterojunction with S-scheme structureand oxygen defects: In-situ construction and photocatalytic behavior for reduction of CO2 with H2O [J].

Miao, Zerui ;

Zhang, Yanfeng ;

Wang, Ning ;

Xu, Peng ;

Wang, Xuxu .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2022, 620 :407-418

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