Application of molybdenum hexacarbonyl in organic synthesis

被引：1

作者：

Kotha, Sambasivarao ^{[1
]}

Gaikwad, Vidyasagar ^{[2
]}

Chaurasia, Usha Nandan ^{[2
]}

机构：

[1] NMIMS Univ, Sunandan Divatia Sch Sci SVKMs, Dept Chem, Ville Parle West, Mumbai 400056, India

[2] Indian Inst Technol, Dept Chem, Mumbai 400076, India

来源：

TETRAHEDRON | 2024年 / 167卷

关键词：

Pauson-Khand reaction; cyclopentenone; Epoxidation; Carbonyl insertion; Cycloaddition; PAUSON-KHAND CYCLOADDITION; ONE-POT SYNTHESIS; 2+2+2 CYCLOTRIMERIZATION; CARBONYLATIVE SYNTHESIS; BENZOSULTINE-SULFONE; DERIVATIVES; CATALYSTS; STRATEGY; ROUTE; ACIDS;

D O I：

10.1016/j.tet.2024.134264

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Here, we describe the role of Mo(CO)6 in various organic transformations such as Pauson-Khand reaction, carbonyl insertion, epoxidation, oxidation, hydrogenation, reduction, [2 + 2+2] cycloaddition, and cyclization sequences. An overview of the reagent's utility and potential is presented in this review, which presents some natural products as well as other relevant compounds. Many reactions and processes are not possible if we use other catalysts. The reactions facilitated by Mo(CO)6 also improve the outcome positively.

引用

页数：14

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