Application of molybdenum hexacarbonyl in organic synthesis

被引：1

作者：

Kotha, Sambasivarao ^{[1
]}

Gaikwad, Vidyasagar ^{[2
]}

Chaurasia, Usha Nandan ^{[2
]}

机构：

[1] NMIMS Univ, Sunandan Divatia Sch Sci SVKMs, Dept Chem, Ville Parle West, Mumbai 400056, India

[2] Indian Inst Technol, Dept Chem, Mumbai 400076, India

来源：

TETRAHEDRON | 2024年 / 167卷

关键词：

Pauson-Khand reaction; cyclopentenone; Epoxidation; Carbonyl insertion; Cycloaddition; PAUSON-KHAND CYCLOADDITION; ONE-POT SYNTHESIS; 2+2+2 CYCLOTRIMERIZATION; CARBONYLATIVE SYNTHESIS; BENZOSULTINE-SULFONE; DERIVATIVES; CATALYSTS; STRATEGY; ROUTE; ACIDS;

D O I：

10.1016/j.tet.2024.134264

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Here, we describe the role of Mo(CO)6 in various organic transformations such as Pauson-Khand reaction, carbonyl insertion, epoxidation, oxidation, hydrogenation, reduction, [2 + 2+2] cycloaddition, and cyclization sequences. An overview of the reagent's utility and potential is presented in this review, which presents some natural products as well as other relevant compounds. Many reactions and processes are not possible if we use other catalysts. The reactions facilitated by Mo(CO)6 also improve the outcome positively.

引用

页数：14

共 50 条

[1] SYNTHESIS OF 7-DEHYDROCHOLESTEROL THROUGH HEXACARBONYL MOLYBDENUM CATALYZED ELIMINATION REACTION
Rahman, Faiz Ur
Tan, Tian Wei
BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, 2011, 25 (02) : 247 - 254
[2] Molybdenum compounds in organic synthesis
Khusnutdinov, Ravil I.
Oshnyakova, Tatyana M.
Dzhemilev, Usein M.
RUSSIAN CHEMICAL REVIEWS, 2017, 86 (02) : 128 - 163
[3] Application of the Nicholas reaction to the synthesis of dicobalt hexacarbonyl complexed diyne ethers
Amin, Jahangir
Motevalli, Majid
Richards, Christopher J.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2015, 776 : 43 - 50
[4] Application of organometallics in organic synthesis
Kotha, Sambasivarao
Meshram, Milind
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 874 : 13 - 25
[5] Synthesis ofN-Heterocycles by Reductive Cyclization of Nitroalkenes Using Molybdenum Hexacarbonyl as Carbon Monoxide Surrogate
Su, Zhiyou
Liu, Bo
Liao, Hongze
Lin, Hou-Wen
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2020, 2020 (26) : 4059 - 4066
[6] Preparation and Application of Vinamidinium Salts in Organic Synthesis
Mao, Yu
Tian, Shaixiao
Zhang, Wei
Xu, Guangyu
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2016, 36 (04) : 700 - 710
[7] Application of Hydrolase Catalytic Promiscuity in Organic Synthesis
Ge, Xin
Lai, Yifeng
Chen, Xinzhi
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2013, 33 (08) : 1686 - 1696
[8] Epoxidation catalysts prepared by encapsulation of molybdenum hexacarbonyl in UiO-66(Zr/Hf)-type metal-organic frameworks
Gomes, Diana P.
Silva, Andreia F.
Gomes, Ana C.
Neves, Patricia
Valente, Anabela A.
Goncalves, Isabel S.
Pillinger, Martyn
MICROPOROUS AND MESOPOROUS MATERIALS, 2022, 330
[9] Formation of Pt-Based Alloy Nanoparticles Assisted by Molybdenum Hexacarbonyl
Leteba, Gerard M.
Mitchell, David R. G.
Levecque, Pieter B. J.
van Steen, Eric
Lang, Candace I.
NANOMATERIALS, 2021, 11 (07)
[10] Synthesis of 4-Quinolones via a Carbonylative Sonogashira Cross-Coupling Using Molybdenum Hexacarbonyl as a CO Source
Akerbladh, Linda
Nordeman, Patrik
Wejdemar, Matyas
Odell, Luke R.
Larhed, Mats
JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (03) : 1464 - 1471

← 1 2 3 4 5 →