Role of Hydrogen Transfer in Functional Molecular Materials and Devices

被引：1

作者：

Zhang, Enyu ^{[1
]}

Bai, Liping ^{[1
]}

Chen, Zhiping ^{[1
]}

Zhang, Aobo ^{[1
]}

Tang, Yingbo ^{[1
]}

Ran, Jushang ^{[1
]}

Wang, Shuai ^{[1
]}

Wang, Jinying ^{[1
]}

Jia, Chuancheng ^{[1
]}

Guo, Xuefeng ^{[1
,2
]}

机构：

[1] Nankai Univ, Inst Modern Opt, Coll Elect Informat & Opt Engn, Ctr Single Mol Sci,Frontiers Sci Ctr New Organ Mat, Tianjin 300350, Peoples R China

[2] Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Natl Biomed Imaging Ctr, Beijing 100871, Peoples R China

来源：

PRECISION CHEMISTRY | 2025年 / 3卷 / 05期

基金：

中国国家自然科学基金; 国家重点研发计划;

关键词：

Hydrogen transfer; Proton transfer; Hydridetransfer; Molecular electronics; Single-moleculedevice; Organic frameworks; Molecular membrane; INTRAMOLECULAR PROTON-TRANSFER; COUPLED ELECTRON-TRANSFER; C-H FUNCTIONALIZATION; ROOM-TEMPERATURE; ATOM TRANSFER; INDUCED TAUTOMERIZATION; BOND FUNCTIONALIZATION; RADICAL TRANSLOCATION; OXIDATION; EFFICIENT;

D O I：

10.1021/prechem.4c00097

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogen transfer is a fundamental chemical process critical to the design and application of organic molecules and functional devices. By uncovering the dynamic interactions between atoms within molecules, hydrogen transfer research offers innovative pathways for creating advanced functional materials and devices. These advancements have driven progress in areas such as optoelectronics, molecular switches, and bioimaging. This review explores the various forms of hydrogen transfer, including hydrogen atom, proton, and hydride transfer, highlighting their mechanisms and key reactions. It also examines the integration of these processes into molecular devices, including single-molecule systems, molecular films, and organic frameworks. Future directions emphasize precise control of hydrogen transfer pathways, development of highly selective and efficient reaction systems, and the design of robust devices based on these processes. These efforts aim to enhance device performance and broaden applications in intelligent materials, integrated functions, and information technology.

引用

页码：233 / 260

页数：28

共 160 条

[1] Tandem 1,5-Hydride Shift/6p Electrocyclization of Ketenimines and Carbodiimides Substituted with Cyclic Acetal and Dithioacetal Functions: Experiments and Computations [J].