Syntheses, structures and antioxidant activities of two new Cu(II) complexes with a benzimidazole schiff base ligand

被引：2
|
作者：
Hu, Dong-Cheng [1 ]
Chen, Li-Wei [1 ]
Yang, Yun-Xia [1 ]
Liu, Jia-Cheng [1 ]
机构：
[1] Northwest Normal Univ, Key Lab Ecoenvironm Related Polymer Mat, Key Lab Polymer Mat Gansu Prov, Key Lab Bioelectrochem & Environm Anal Gansu Prov,, Lanzhou 730070, Peoples R China
来源：
INORGANIC AND NANO-METAL CHEMISTRY | 2023年 / 53卷 / 07期
基金：
中国国家自然科学基金;
关键词：
Cu(II) complexes; Benzimidazole schiff base; Crystal structures; Antioxidant activities; SUPEROXIDE-DISMUTASE; CRYSTAL-STRUCTURES; 1,4,7-TRIAZACYCLONONANE; IMIDAZOLE; MODEL;
D O I：
10.1080/15533174.2013.843562
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new copper complexes based on aschiff base ligand (N-(methyl-2- benzimidazolmethylidene)-2-hydroxyaniline (L), [CuL2NO3]NO3<middle dot>2EtOH (1),and [CuLNO3](2)<middle dot>2EtOH (2) have been synthesized and characterized by elemental, spectroscopic methods and X-ray structural analyses. The results of single-crystal X-ray diffraction analyses indicate that 1 is a mononuclear structure; 2 is a binuclear units. These structures are further extended 3D supramolecular frameworks by the hydrogen bonds and pi...pi stacking interactions in the solid state. Furthermore, the antioxidant activities of L, 1 and 2 were also studied.
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页数：21
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