Effect of Extensive Solar Ultra-Violet Irradiation on the Durability of High-Density Polyethylene- and Polypropylene-Based Wood-Plastic Composites

被引:0
作者
Siddiqui, Mohammad N. [1 ]
Redhwi, Halim H. [2 ]
Andrady, Anthony L. [3 ]
Furquan, Sarfaraz A. [4 ]
Hussain, Syed [5 ]
机构
[1] King Fahd Univ Petr & Minerals, Chem Dept & IRC Refining & Adv Chem, Dhahran 31261, Saudi Arabia
[2] King Fahd Univ Petr & Minerals, Chem Engn Dept & IRC Refining & Adv Chem, Dhahran 31261, Saudi Arabia
[3] North Carolina State Univ, Dept Chem & Biomol Engn, Raleigh, NC 27607 USA
[4] King Fahd Univ Petr & Minerals, Mech Engn Dept, Dhahran 31261, Saudi Arabia
[5] King Fahd Univ Petr & Minerals, Dhahran Techno Valley, Dhahran 31261, Saudi Arabia
关键词
wood-plastic composites; weatherability; HDPE; PP; MECHANICAL-PROPERTIES; TENSILE PROPERTIES; FLOUR; SURFACE; DEGRADATION; RESISTANCE; MORPHOLOGY; COLOR;
D O I
10.3390/polym17010074
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The natural and laboratory-accelerated weathering of wood-plastic composites (WPCs) based on high-density polyethylene (HDPE) and polypropylene (PP) plastics was investigated in this study. Injection molded samples of WPCs with different loadings of wood fiber ranging from 0 to 36 wt.% of wood were subjected to laboratory-accelerated weathering and natural weathering. The integrity of samples weathered to different extents was tested using a standard tensile test and surface hardness test to investigate the dependence of these properties on the duration of weathering exposure. Tensile data were used to identify the loading of wood fibers in either plastic matrix that afforded superior ultra-violet (UV) stability. Tensile measurements under uniaxial strain yielded average values of tensile strength (TS), low-extension modulus (E), and elongation at break (EB). Both natural weathering outdoors and accelerated weathering in the laboratory showed that the TS and EB decreased while the E increased with the duration of exposure for all samples tested. The change in the average TS of composites with the duration of exposure offers valuable insights. The correlation between the tensile and hardness data for the WPC samples was explored. After naturally weathering at two exposure sites, the hardness of the WPCs was found to decrease between 8% to 12.5%, depending on the composition and exposure location parameters. Furthermore, no marked difference in performance with increasing wood fiber beyond 18 wt.% was observed. WPCs can be a key parameter in environmental sustainability by being used in the building and packaging industries, which reduces carbon emissions and waste generation.
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页数:16
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