Pd-catalyzed enantioselective hydroesterification of vinyl arenes on water

被引:2
作者
Li, Junhua [1 ]
Min, Yaqian [1 ]
Shi, Yian [1 ]
机构
[1] Changzhou Univ, Inst Nat & Synthet Organ Chem, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China
基金
中国国家自然科学基金;
关键词
ORGANIC-REACTIONS; ARYL OLEFINS; PALLADIUM; HYDROCARBOXYLATION; TPPTS;
D O I
10.1039/d4nj02253j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An efficient Pd-catalyzed asymmetric hydroesterification of vinyl arenes on water is reported. A variety of phenyl 2-arylpropanoates can be obtained in good yields with high b/l ratios and ee's with phenyl formate or CO as a carbonyl source. (R)-DTBM-SEGPHOS was found to be an effective ligand for the reaction under aqueous conditions. The hydrophobicity of the ligand appeared to be crucial to the hydroesterification reaction, which likely proceeded "on water".
引用
收藏
页码:17381 / 17384
页数:4
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