As-Doped Polycrystalline CdSeTe: Localized Defects, Carrier Mobility and Lifetimes, and Impact on High-Efficiency Solar Cells

被引：2

作者：

Scajev, Patrik ^{[1
]}

Nardone, Marco ^{[2
]}

Reich, Carey ^{[3
]}

Farshchi, Rouin ^{[3
]}

McReynolds, Kevin ^{[4
]}

Krasikov, Dmitry ^{[4
]}

Kuciauskas, Darius ^{[5
]}

机构：

[1] Vilnius Univ, Inst Photon & Nanotechnol, Fac Phys, LT-10257 Vilnius, Lithuania

[2] Bowling Green State Univ, Dept Phys, Bowling Green, OH 43403 USA

[3] Calif Technol Ctr, Solar 1, Santa Clara, CA 95050 USA

[4] Adv Res, Solar 1, Perrysburg, OH 43551 USA

[5] Chem & Nanosci Ctr, Natl Renewable Energy Lab, Golden, CO 80401 USA

来源：

ADVANCED ENERGY MATERIALS | 2025年 / 15卷 / 10期

关键词：

CdTe; characterization; loss analysis; thin film solar cells; TIME-RESOLVED PHOTOLUMINESCENCE; CADMIUM TELLURIDE; LIMIT;

D O I：

10.1002/aenm.202403902

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The efficiency potential for single-junction photovoltaics (PV) is described by the detailed balance model, which requires the elimination of nonradiative recombination and perfect minority carrier collection. Improvements in GaAs, Si, and perovskite PV follow this model. It might be more complex for CdTe, a leading thin-film PV technology. While lifetime, passivation, and doping goals for 25% efficient CdTe solar cells are largely reached, voltage is approximate to 20% below the detailed balance limit. Why is that? In Se-alloyed CdSexTe1-x (Se is required for >20% efficiency) additional losses can occur due to electrostatic and bandgap fluctuations and due to electronic trap states. To understand mechanisms limiting CdSeTe solar cell performance and to suggest improvements, carrier dynamics, and transport in CdSexTe1-x with variation in Se composition and as doping is analyzed. It is shown that trapping, likely due to anion-site defects and their complexes, is correlated with low charge carrier mobility of 0.1-0.6 cm(2) (Vs)(-1). Even with 1000 ns charge carrier lifetimes, carrier diffusion length is less than the absorber thickness, reducing efficiency to approximate to 23%. Device simulations are used to analyze the performance of CdSexTe1-x solar cells; thermodynamic models are not sufficient for absorbers with electronic disorder and trapping.

引用

页数：12