Recent Advances in the Application of Carbon Dioxide Radical Anion

被引：1

作者：

Hou, Jing ^{[1
]}

Huang, Yan ^{[2
]}

Li, Hao ^{[1
]}

Wan, Yuancui ^{[1
]}

Shao, Yu ^{[1
]}

Zhan, Lewu ^{[1
]}

Wang, Dinghai ^{[1
]}

Li, Bindong ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Sch Chem & Chem Engn, Nanjing 210094, Peoples R China

[2] Huanggang Normal Univ, Sch Chem & Chem Engn, Huanggang 438000, Hubei, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 44卷 / 10期

基金：

中国国家自然科学基金;

关键词：

carbon dioxide radical anion; Giese radical addition; defluorinative alkylation; reductive degradation; ONE-ELECTRON REDUCTION; ELECTROCHEMICAL REDUCTION; DEFLUORINATIVE ALKYLATION; UNACTIVATED ALKENES; FORMATE SALTS; HYDROCARBOXYLATION; CO2; CARBOXYLATION; CR(VI); UV;

D O I：

10.6023/cjoc202404039

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Carbon dioxide radical anion (CO2 center dot-) is an active chemical intermediate with strong reduction ability, which is used widely as C1-building block and single electron reducing reagent in organic synthesis. CO2 and formic acid or formate salts are common source of CO2 center dot- . CO(2)(center dot- )can be generated by either direct reduction of CO(2 )or hydrogen atom transfer (HAT) of formate salts. The production, characterization methods and application of CO2 center dot- are summarized, and the insights are provided into the prospects in this field.

引用

页码：3117 / 3135

页数：19

共 97 条

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