Rational Synthesis of UiO-66 and its Application in the Hydrogenation Reaction of p-Chloronitrobenzene

被引:2
作者
Andreeva, Anastasia V. [1 ,4 ]
Baimuratova, Rose K. [1 ]
Dorokhov, Victor G. [2 ]
Akkuratov, Alexander V. [3 ]
Shilov, Gennadii V. [1 ]
Kugabaeva, Gulsara D. [1 ,5 ]
Golubeva, Nina D. [1 ]
Dzhardimalieva, Gulzhian I. [2 ,5 ]
机构
[1] Russian Acad Sci, Fed Res Ctr Problems Chem Phys & Med Chem, Chernogolovka 142432, Moscow Region, Russia
[2] Russian Acad Sci, Fed Res Ctr Problems Chem Phys & Med Chem, Lab Catalyt Synth Organ Cpds, Chernogolovka 142432, Moscow Region, Russia
[3] Russian Acad Sci, Fed Res Ctr Problems Chem Phys & Med Chem, Dept Polymers & Composite Mat, Lab Photosensit & Electroact Mat, Chernogolovka 142432, Moscow Region, Russia
[4] Lomonosov Moscow State Univ, Dept Fundamental Phys & Chem Engn, Moscow 119991, Russia
[5] Nat Res Univ, Moscow Aviat Inst, Moscow 125993, Russia
来源
EURASIAN JOURNAL OF CHEMISTRY | 2024年 / 115卷 / 03期
关键词
metal-organic frameworks; UiO-66; heterogeneous catalysts; Pd/UiO-66; hydrogenation; p-Chloronitrobenzene; zirconium complexes; terephthalic acid; hydrogenation of nitroderivatives; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; TEMPERATURE SYNTHESIS; GAS-STORAGE; ADSORPTION; DESIGN; MOFS; SEPARATION; MICROWAVE; CATALYST;
D O I
10.31489/2959-0663/3-24-10
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hydrogenation is a widely used reaction in the oil processing and industrial organic synthesis. UiO-66 is a promising porous organic-inorganic material that can be used as a support for catalytically active particles. The key part in the application of highly porous UiO-66 is the search of a simple synthesis method that meets international environmental standards. In this study, a "rational" method for the synthesis of MOFs was used to produce UiO-66. The use of pre-synthesized multinuclear zirconia clusters facilitates the synthesis of the desired network topology, enabling the process to be conducted in an environmentally friendly aqueous solution. The effects of reaction temperature, linker volume concentration and solvent type on the specific surface area and thermal properties were also evaluated in this work. We studied the composition, structure and physicochemical properties of the obtained compounds by IR spectroscopy, TGA and XRD analysis. The proposed procedure has been shown to yield UiO-66 with high specific surface area (S-BET = 885 m(2)/g) and to extend the thermal stability range up to 490 degrees C. The post-synthetic modification of the obtained UiO-66 with the introduction of catalytically active Pd (Pd/UiO-66) was carried out, and high selectivity (83,0 %) of the obtained Pd/UiO-66 exhibited high selectivity in the hydrogenation reaction of p-chloronitrobenzene into p-chloroaniline in comparison with the traditional Pd/Al2O3.
引用
收藏
页码:92 / 108
页数:17
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