Perfluorinated Carbon Chain Length Drives Uptake of Diverse Per- and Polyfluoroalkyl Substances in Field-Deployed Passive Samplers

Per- and polyfluoroalkyl substances (PFAS) are a group of compounds of high concern due to their ubiquity, persistence, and adverse health impacts. With a diversity of chemical structures and properties, detection tools are needed to capture as many PFAS as possible. In this study, a microporous polyethylene tube (MPT) passive sampler was calibrated for 25 target compounds, 8 suspect PFAS, and extractable organofluorine (EOF) during 1-2 week deployments in groundwater, freshwater river, and estuary contaminated by aqueous film-forming foam (AFFF). Targeted analysis, suspect screening, and EOF were performed on passive and grab samples to derive sampling rates, R s. Median measured and fluorine-normalized estimated EOF R s in groundwater (7.1 vs 8.4 mL day-1 respectively) and river water (55 vs 66 mL day-1 respectively) were within 20% of each other. For suspect PFAS, R s were similar to targeted PFAS of alike functional group chemistry and perfluorinated carbon chain length. For example, for 6:2 and 8:2 FTSAS-sulfoxide, estimated R s values were 1.8 and 6.0 mL day-1, respectively, similar to R s measured for 6:2 and 8:2 FTS of 2.2 and 6.3 mL day-1. These results suggest that targeted and suspect PFAS and EOF are predictably taken up by MPT samplers, expanding passive sampling capabilities.