Synthesis, structure, magnetic and electrocatalytic properties of a dinuclear triazendio-copper(II) complex

被引：0

作者：

Yang, Hao ^{[1
]}

Du, Juan ^{[1
]}

Wang, Chun-Li ^{[1
]}

Xie, Ze-Hao ^{[1
]}

Zhan, Shu-Zhong ^{[1
]}

机构：

[1] South China Univ Technol, Coll Chem & Chem Engn, Guangzhou 510640, Peoples R China

来源：

INORGANIC AND NANO-METAL CHEMISTRY | 2023年 / 53卷 / 07期

基金：

美国国家科学基金会;

关键词：

Triazendio-copper(II) complex; magnetic behavior; electrocatalyst for hydrogen evolution; CATALYZING HYDROGEN EVOLUTION; GENERATING HYDROGEN; ACETIC-ACID; TRIAZENIDE COMPLEXES; OXIDATIVE ADDITION; ELECTRO-CATALYST; NICKEL-COMPLEX; COPPER COMPLEX; REDUCTION; WATER;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new dinuclear copper(II) complex, [Cu2L4] is obtained from the reaction of CuCl2 & sdot;2H2O with a triazenido compound, 1-[(2-methoxy) phenyl]-3-[2-pyridine] triazene (HL), which is prepared by the reaction of o-anisidine anthranilate, sodium nitrite and 2-aminopyridine. Magnetic investigation shows that there is an antiferromagnetic exchange interaction between copper(II) ions. Electrochemical studies exhibit that [Cu2L4] can serve as catalyst for hydrogen generation both from acetic acid with a turnover frequency (TOF) of 48.95 moles of hydrogen per mole of catalyst per hour (mol H2/mol catalyst/h) at an overpotential (OP) of 941.6 mV, and a phosphate buffer (pH 7.0) with a TOF of 814.79 mol H2/mol catalyst/h at an OP of 836.7 mV.

引用

页码：699 / 707

页数：9

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