Third-order nonlinear optical studies and investigation of the hydrogen bond network in 2-picolinic perchloric acid using neutron diffraction

被引：0

作者：

George, Merin ^{[1
]}

John, Jerin Susan ^{[1
]}

Gowri, S. ^{[2
]}

Priya, S. ^{[2
]}

Alex, Javeesh ^{[1
]}

Nayana, D. A. ^{[3
]}

Philip, Bessy Mary ^{[4
]}

Choudhury, R. R. ^{[5
]}

Chitra, R. ^{[5
]}

Sajan, D. ^{[1
]}

机构：

[1] Bishop Moore Coll, Ctr Sustainable Energy & Environm Technol CET, Dept Phys, Mavelikara 690110, Kerala, India

[2] Cauvery Coll Women, Dept Phys, Trichy 620018, India

[3] TKM Coll Arts & Sci, Dept Phys, Kollam, Kerala, India

[4] Bishop Moore Coll, Dept Chem, Alappuzha 690110, Kerala, India

[5] Bhabha Atom Res Ctr, Solid State Phys Div, Trombay 85,Room 307,CMPD Bldg, Mumbai 400085, Maharashtra, India

来源：

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS | 2025年 / 36卷 / 11期

关键词：

CRYSTAL-STRUCTURE; SINGLE-CRYSTAL; GROWTH; NLO; ABSORPTION; BENZYLIDENEANILINE; PICRATE;

D O I：

10.1007/s10854-025-14693-3

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

The single crystals of 2-picolinic perchloric acid (2-PPCA), a notable nonlinear optical (NLO) material, were successfully cultivated using a slow evaporation method. A single crystal of size 15 x 14 x 6 mm3 was grown and the crystalline structure was precisely confirmed through single-crystal X-ray and neutron diffractions. In this study, we meticulously retrieved and analysed the NMR, FT-IR, Raman and UV-Vis spectra to gain deeper insights into their characteristics. Our study also provides a comprehensive examination of the nonlinear optical characteristics of 2-picolinic perchloric acid. The limiting threshold of the 2-picolinic perchloric acid solvent media and its third-order NLO features were investigated using the z-scan technique. The results from the z-scan analysis demonstrate that 2-picolinic perchloric acid is an excellent alternative for optoelectronic and photonic device design usances with a 2PA coefficient value of 17.5 x 10-12 m/W.

引用

页数：15

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