A Feasible Strategy for High-Performance Aqueous Zinc-Ion Batteries: Introducing Conducting Polymer

Aqueous zinc ion batteries (AZIBs) offer great potential for large-scale energy storage because of their high safety, low cost and acceptable energy density. However, the cycle life of AZIBs is inevitably affected by parasitic reactions and dendritic growth caused by multiple factors such as electrode, electrolyte and separator, which pose significant obstacles to the practical application of AZIBs. To address these challenges, conducting polymer (CP) based materials have gained widespread attention in the realm of rechargeable batteries due to the adjustable band gap, controllable morphology, and excellent flexibility of CPs. In particular, CPs exhibit remarkable conductivity, low dimensionality, and doping characteristics, making them highly promising for integration into the AZIB system. In this review, the problems associated with the cathode, anode, electrolyte, and separator of AZIBs are discussed, and the application of CPs for their modification is summarized. The review provides a comprehensive analysis of the action mechanisms involved in the CP modification process and offers valuable insights for the design and development of CPs that can be effectively utilized in AZIBs. Additionally, the review presents a promising outlook of this research field, aiming to further advance the application of low-cost and high-performance CPs and their composites in AZIBs. Conducting polymer (CP) materials are essential in the modification of aqueous zinc ion batteries (AZIBs) because of their adjustable band gap, controllable morphology and flexibility. This review analyzes the problems of cathode, anode, electrolyte and separator of AZIBs, summarizes the application of CPs in the modification of AZIBs and discusses the current challenges and future application prospects of CP-based materials. image