Enhancing Carbon Fiber-Reinforced Polymers' Performance and Reparability Through Core-Shell Rubber Modification and Patch Repair Techniques

被引:1
作者
Semitekolos, Dionisis [1 ]
Terzopoulou, Sofia [1 ]
Charitidis, Costas [1 ]
机构
[1] Natl Tech Univ Athens, Sch Chem Engn, RNANO Lab, Res Lab Adv Composite Nanomat & Nanotechnol, 9 Heroon Polytech st, GR-15773 Zografos, Athens, Greece
关键词
CFRPs; core-shell rubber; fracture toughness; impact modifiers; patch repair; PARTICLES;
D O I
10.3390/polym17030407
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Carbon fiber-reinforced polymers (CFRPs) are widely used in high-performance applications, but their inherent brittleness and susceptibility to impact damage remain critical challenges. This study investigated the effect of core-shell rubber (CSR) particles as impact modifiers on the mechanical properties of CFRPs and evaluated patch repair techniques for damaged CFRP panels. Mechanical tests, including flexural, tensile, short-beam, fracture toughness, and impact tests, were conducted on reference and CSR-modified specimens to assess their structural performance. The CSR-modified samples demonstrated significant improvements in energy absorption and fracture toughness, with a 50% increase in impact strength and up to 181% improvement in absorbed energy during Mode I fracture testing. However, slight reductions in flexural and tensile strengths were observed due to the softening effect of CSR particles. Fracture surface analysis revealed distinct failure mechanisms, with Scanning Electron Microscopy imaging showing consistent fiber pull-out behavior in tensile and flexural tests, but more stable delamination propagation in CSR-modified specimens during short-beam shear tests. Patch repair effectiveness was assessed through drop-weight impact tests on damaged panels repaired with patches containing CSRs of two thicknesses. Patches of equal thickness to the damaged panel successfully restored structural integrity and enhanced energy absorption by 37% compared with the reference samples, while thinner patches (as a suggestion to reduce production costs) failed to withstand impact loads effectively. Non-destructive testing (NDT) via ultrasonic C-scans confirmed reduced delamination and damage depth in CSR-modified repaired panels, validating the toughening effect of CSR particles. These findings demonstrate the potential of CSR-modified resins to improve CFRPs' performance and provide effective repair solutions for extending the service life of damaged composite structures, rendering them especially suitable for applications demanding high damage tolerance and durability, including aerospace structures, automotive body panels, and energy-absorbing crash components.
引用
收藏
页数:23
相关论文
共 29 条
[1]  
[Anonymous], 2022, D5528/D5528M-21
[2]  
[Anonymous], 2023, PlasticsDetermination of Izod Impact Strength
[3]  
[Anonymous], 2015, Test Method for Measuring the Damage Resistance of a Fiber-Reinforced Polymer Matrix Composite to a Drop-Weight Impact Event, DOI [10.1520/D7136D7136M-12, DOI 10.1520/D7136D7136M-12]
[4]  
[Anonymous], 2022, ASTM D2344/D2344M-22
[5]   Recent Progress in Carbon Fiber Reinforced Polymers Recycling: A Review of Recycling Methods and Reuse of Carbon Fibers [J].
Antonio Butenegro, Jose ;
Bahrami, Mohsen ;
Abenojar, Juana ;
Angel Martinez, Miguel .
MATERIALS, 2021, 14 (21)
[6]  
ASTM Standard, 2017, STANDARD TEST METHOD, DOI DOI 10.1520/D0790-17.2
[7]   Cyclodextrin as sizing for carbon fibers: new bonding mechanism improves adhesion in carbon fiber reinforced epoxy resin [J].
Becker-Staines, Anna ;
Bremser, Wolfgang ;
Troester, Thomas .
HELIYON, 2020, 6 (04)
[8]   Toughened carbon fibre-reinforced polymer composites with nanoparticle-modified epoxy matrices [J].
Carolan, D. ;
Ivankovic, A. ;
Kinloch, A. J. ;
Sprenger, S. ;
Taylor, A. C. .
JOURNAL OF MATERIALS SCIENCE, 2017, 52 (03) :1767-1788
[9]   The mechanical properties and toughening mechanisms of an epoxy polymer modified with polysiloxane-based core-shell particles [J].
Chen, J. ;
Kinloch, A. J. ;
Sprenger, S. ;
Taylor, A. C. .
POLYMER, 2013, 54 (16) :4276-4289
[10]   Effect of Core-Shell Rubber Nanoparticles on the Mechanical Properties of Epoxy and Epoxy-Based CFRP [J].
Glaskova-Kuzmina, Tatjana ;
Stankevics, Leons ;
Tarasovs, Sergejs ;
Sevcenko, Jevgenijs ;
Spacek, Vladimir ;
Sarakovskis, Anatolijs ;
Zolotarjovs, Aleksejs ;
Shmits, Krishjanis ;
Aniskevich, Andrey .
MATERIALS, 2022, 15 (21)