Preparation and characterization of core-shell structured CaCO3-SiO2 and hollow silica nanoparticles and evaluation of their effects on cement mortar properties

CaCO3-SiO2 particles having a core-shell nanostructure were produced by a modified Stober process using CTAB as a surfactant. Then, a porous structure composed of a silica shell was formed after the removal of the CaCO3 cores as templates from the nanocomposite. To evaluate phase constitutions and microstructures of prepared nanoparticles, XRD, TEM, and FESEM-EDX techniques were utilized. The main aim of this work was to examine the usability of prepared CaCO3-SiO2 and SiO2 hollow shell nanoparticles instead of OPC in structural applications. In this way, the mixtures of cement mortar were made by partial replacement of 1% of cement mass with prepared nanoparticles. The amounts of calcium hydroxide (CH), bound water, and calcium carbonate for the prepared mortars have been calculated after 7 and 28 days of hydration through thermal analysis of TG/DTG. The results indicated that the CH content decreased by adding prepared nanoparticles as a cement replacement. As CaCO3-SiO2 and hollow SiO2 nanoparticles were used, the compressive strengths of mortars were enhanced by 34 and 59%, respectively, after 28 days, which were higher than the increasing influences on flexural strengths (29 and 55%). The increasing intensity of the XRD peaks related to the C-S-H phases and the decline of the orientation index of CH in a mortar containing silica shell suggest that hydration was further completed, leading to a strength improvement. The SEM micrographs indicated that the addition of prepared nanostructures improved the interface properties inside mortar and caused the microstructure to be denser.