Recent Advances in Aromatic Hydroxylation to Phenol and Hydroquinone Using H2O2

被引：2
作者：
Naranov, Evgeny [1 ]
Ramazanov, Dzhamalutdin [1 ]
Agliullin, Marat [2 ]
Sinyashin, Oleg [3 ]
Maximov, Anton [1 ]
机构：
[1] Russian Acad Sci, Topchiev Inst Petrochem Synth, Leninskiy Prospekt 29, Moscow 119991, Russia
[2] UFRC RAS IPC RAS, Inst Petrochem & Catalysis, Prospekt Oktyabrya st 141, Ufa 450075, Russia
[3] Russian Acad Sci, Fed Res Ctr, Kazan Sci Ctr, Lobachevskogo St 2-31, Kazan 420111, Russia
来源：
CATALYSTS | 2024年 / 14卷 / 12期
关键词：
hydroxylation; phenol; hydroquinone; catechol; PHOTOCATALYTIC SELECTIVE OXIDATION; MESOPOROUS MOLECULAR-SIEVES; HIGH CATALYTIC-ACTIVITY; LIQUID-PHASE OXIDATION; HYDROGEN-PEROXIDE; TITANIUM SILICALITE-1; BENZENE HYDROXYLATION; TERNARY HYDROTALCITES; STRUCTURAL-PROPERTIES; NITROUS-OXIDE;
D O I：
10.3390/catal14120930
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Direct hydroxylation of aromatics and phenol processes using green oxidants plays an important role in the petrochemical industry. High selectivity towards hydroquinone is usually hard to achieve due to catechol formation and catalyst deactivation. Herein, we showed the recent studies devoted to selective phenol hydroxylation via oxidation using H2O2. This review summarizes progress that has been achieved in this area. Briefly, aromatic hydroxylation on heterogeneous catalysts, phenol hydroxylation on Ti-containing and supported catalysts, photocatalytic hydroxylation, and new approaches toward phenol hydroxylation have been reviewed.
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页数：23
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