Recent Advances in Aromatic Hydroxylation to Phenol and Hydroquinone Using H2O2

被引：0
|
作者：
Naranov, Evgeny [1 ]
Ramazanov, Dzhamalutdin [1 ]
Agliullin, Marat [2 ]
Sinyashin, Oleg [3 ]
Maximov, Anton [1 ]
机构：
[1] Russian Acad Sci, Topchiev Inst Petrochem Synth, Leninskiy Prospekt 29, Moscow 119991, Russia
[2] UFRC RAS IPC RAS, Inst Petrochem & Catalysis, Prospekt Oktyabrya st 141, Ufa 450075, Russia
[3] Russian Acad Sci, Fed Res Ctr, Kazan Sci Ctr, Lobachevskogo St 2-31, Kazan 420111, Russia
来源：
CATALYSTS | 2024年 / 14卷 / 12期
关键词：
hydroxylation; phenol; hydroquinone; catechol; PHOTOCATALYTIC SELECTIVE OXIDATION; MESOPOROUS MOLECULAR-SIEVES; HIGH CATALYTIC-ACTIVITY; LIQUID-PHASE OXIDATION; HYDROGEN-PEROXIDE; TITANIUM SILICALITE-1; BENZENE HYDROXYLATION; TERNARY HYDROTALCITES; STRUCTURAL-PROPERTIES; NITROUS-OXIDE;
D O I：
10.3390/catal14120930
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Direct hydroxylation of aromatics and phenol processes using green oxidants plays an important role in the petrochemical industry. High selectivity towards hydroquinone is usually hard to achieve due to catechol formation and catalyst deactivation. Herein, we showed the recent studies devoted to selective phenol hydroxylation via oxidation using H2O2. This review summarizes progress that has been achieved in this area. Briefly, aromatic hydroxylation on heterogeneous catalysts, phenol hydroxylation on Ti-containing and supported catalysts, photocatalytic hydroxylation, and new approaches toward phenol hydroxylation have been reviewed.
引用
收藏
页数：23
相关论文
共 50 条
  • [1] Catalysis of metalloporphyrins for selective hydroxylation of phenol by H2O2
    Zeng, Hai-Qiang
    Jiang, Quan
    Zhu, Yun-Fei
    Yan, Xu-Hui
    Liang, Xue-Bo
    Hu, Hai-Yang
    Liu, Qiang
    Lin, Wei-ying
    Guo, Can-Cheng
    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2006, 10 (02) : 96 - 103
  • [2] SELECTIVE HYDROXYLATION OF AROMATIC-COMPOUNDS WITH H2O2
    BULL, RA
    MCEUEN, BK
    ANNARELLI, DC
    BYERS, LR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1984, 187 (APR): : 224 - INOR
  • [3] Recent Advances in the Direct Synthesis of H2O2
    Lewis, Richard J.
    Hutchings, Graham J.
    CHEMCATCHEM, 2019, 11 (01) : 298 - 308
  • [4] Catalytic Reaction Mechanism for Hydroxylation of Benzene to Phenol with H2O2/O2 as Oxidants
    Zhang, Mingjue
    Fan, Changpo
    Wang, Long
    Wu, Xuejing
    Zhou, Yu
    Wang, Jun
    PROGRESS IN CHEMISTRY, 2022, 34 (05) : 1026 - 1041
  • [5] Direct hydroxylation of benzene to phenol by supported vanadium substitution polyoxometalates using H2O2 as oxidant
    Yang, Yingwei
    Tang, Ruiren
    RESEARCH ON CHEMICAL INTERMEDIATES, 2018, 44 (10) : 5911 - 5922
  • [6] Direct hydroxylation of benzene to phenol by supported vanadium substitution polyoxometalates using H2O2 as oxidant
    Yingwei Yang
    Ruiren Tang
    Research on Chemical Intermediates, 2018, 44 : 5911 - 5922
  • [7] SOLVENT EFFECTS IN THE HYDROXYLATION OF PHENOL WITH H2O2 OVER TS-1
    THANGARAJ, A
    PUTHOOR, L
    SIVASANKER, S
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1994, 33 (03): : 255 - 258
  • [8] Consequences of Fe speciation in MFI zeolites for hydroxylation of benzene to phenol with H2O2
    Xiao, Peipei
    Wang, Yong
    Kondo, Junko N.
    Yokoi, Toshiyuki
    APPLIED CATALYSIS A-GENERAL, 2019, 579 : 159 - 167
  • [9] Diatomite as high performance and environmental friendly catalysts for phenol hydroxylation with H2O2
    Jia, Yuxin
    Han, Wei
    Xiong, Guoxing
    Yang, Weishen
    SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 2007, 8 (1-2) : 106 - 109
  • [10] Aqueous-phase catalytic hydroxylation of phenol with H2O2 by using a copper incorporated apatite nanocatalyst
    Amedlous, Abdallah
    Amadine, Othmane
    Essamlali, Younes
    Daanoun, Karim
    Aadil, Mina
    Zahouily, Mohamed
    RSC ADVANCES, 2019, 9 (25) : 14132 - 14142
12345