A Cu(II) COORDINATION COMPOUND CONSTRUCTED BY MIXED LIGANDS OF 1,10-PHENANTHROLINE AND CARBOXYLIC ACID: SYNTHESIS, CHARACTERIZATION AND HIRSHFELD SURFACE ANALYSIS

被引：0

作者：

Wang, Huilin ^{[1
,2
]}

Liu, Keming ^{[2
]}

Kong, Zhiguo ^{[1
,2
]}

Zhao, Lina ^{[1
,2
]}

Zhang, Hua ^{[1
,2
]}

机构：

[1] Jilin Normal Univ, Key Lab Preparat & Applicat Environm Friendly Mat, Minist Educ, Changchun 130103, Peoples R China

[2] Jilin Normal Univ, Dept Chem, Siping 136000, Peoples R China

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA | 2025年 / 39卷 / 03期

关键词：

Cu(II); Coordination compound; Hirshfeld surface analysis; DFT calculation; 1,10-phenanthroline; QUANTITATIVE-ANALYSIS; CRYSTAL-STRUCTURE; POLYMERS; COMPLEXES; ZN(II); CO(II);

D O I：

10.4314/bcse.v39i3.4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

. Synthesis and full characterization of a new coordination compound, which was synthesized by mixed ligands under hydrothermal condition, namely [Cu(L)2(phen)2(H2O)2]center dot 4H2O (1) (phen = 1,10-phenanthroline, H2L = 3-carboxy-1-carboxymethyl-2-oxidopyridinium). Cu(II) is six-coordinated in a slightly twisted [CuN2O4] octahedral geometry. 1 displays 2D supramolecular layer, which is further extended into a 3D network by the pi-pi stacking and hydrogen bonds. 3D Hirshfeld surface analysis is combined with 2D fingerprint plots to investigate the contribution of different intermolecular interactions within the crystal. DFT calculations are also performed.

引用

页码：437 / 446

页数：10

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