Molecular Heterogeneous Photocatalysts for Visible-Light-Driven CO2 Reduction

Photoreduction of CO(2 )to high-value chemical fuels presents an effective strategy to reduce reliance on fossil fuels and mitigate climate change. The development of a photocatalyst characterized by superior activity, high selectivity, and good stability is a critical issue for PCR. Molecular heterogeneous photocatalytic systems integrate the advantages of both homogeneous and heterogeneous catalysts, creating a synergistic enhancement effect that increases photocatalytic performance. This review summarizes recent advancements in molecular heterogeneous photocatalysts for CO2 reduction. Much of the discussion focuses on the types of molecular heterogeneous photocatalysts, and their photocatalytic performance in CO2 reduction is summarized. The synthesis strategies for molecular heterogeneous photocatalysts are thoroughly discussed. Finally, the challenges and future prospects of molecular heterogeneous photocatalysts for PCR are addressed.