Unleashing the potential of it-conjugation in organic framework materials for electrochemical energy storage and conversion

被引：8

作者：

Zhu, Rongmei ^{[1
]}

Liu, Limei ^{[1
]}

Zhang, Guangxun ^{[1
]}

Xu, Yuanhang ^{[1
]}

Gu, Yijing ^{[1
]}

Pang, Huan ^{[1
,2
]}

机构：

[1] Yangzhou Univ, Inst Innovat Mat & Energy, Sch Chem & Chem Engn, Yangzhou 225009, Jiangsu, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210023, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2025年 / 532卷

基金：

中国国家自然科学基金;

关键词：

it-Conjugation; Metal-organic framework; Covalent organic framework; Energy storage; Energy conversion; ROOM-TEMPERATURE; CARBON-DIOXIDE; CO2; REDUCTION; IONIC LIQUID; PERFORMANCE; GRAPHENE; ELECTRODE; CATHODE; DESIGN; ELECTROCATALYSIS;

D O I：

10.1016/j.ccr.2025.216498

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Conjugation is an electronic phenomenon in a system where the distribution of it-electrons (or p-electrons) changes due to interactions between atoms in the conjugated structure. The presence of conjugated systems not only has a great impact on the physical properties, such as the ultraviolet absorption spectra, fluorescence spectra, nuclear magnetic resonance, but also plays an important part on the reactivity of the compounds. Conjugated systems composed of different atoms or groups exhibit different degrees of conjugation effects. In this manuscript, the effects of different kinds of it-conjugated structures on organic framework materials are summarized, including it-it, p-it and d-it conjugation. It focuses on recent advancements in the application of energy storage and conversion (ESC) of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) incorporating with it-conjugated structures. Lastly, the opportunities and challenges involved in the structural design and application of it-conjugation in the near future are proposed.

引用

页数：31

共 50 条

[31] Applications of metal-organic framework-graphene composite materials in electrochemical energy storage [J].

Zhang, Mengyao ;

Shan, Yuying ;

Kong, Qingquan ;

Pang, Huan .

FLATCHEM, 2022, 32

[32] Porphyrin-based framework materials for energy conversion [J].

Gu, Jiawei ;

Peng, Yi ;

Zhou, Ting ;

Ma, Jiao ;

Pang, Huan ;

Yamauchi, Yusuke .

NANO RESEARCH ENERGY, 2022, 1 (01)

[33] Covalent Organic Framework Electrocatalysts for Clean Energy Conversion [J].

Lin, Chun-Yu ;

Zhang, Detao ;

Zhao, Zhenghang ;

Xia, Zhenhai .

ADVANCED MATERIALS, 2018, 30 (05)

[34] Conductive metal-organic framework as an emerging platform with electrochemical energy storage [J].

Jiang, Zhaocheng ;

Wang, Shixian ;

Lu, Yiyao ;

Meng, Zhenyang ;

Pang, Huan .

COORDINATION CHEMISTRY REVIEWS, 2025, 544

[35] Research Progress on Graphite-Derived Materials for Electrocatalysis in Energy Conversion and Storage [J].

He, Shuaijie ;

Wu, Mingjie ;

Li, Song ;

Jiang, Zhiyi ;

Hong, Hanlie ;

Cloutier, Sylvain G. ;

Yang, Huaming ;

Omanovic, Sasha ;

Sun, Shuhui ;

Zhang, Gaixia .

MOLECULES, 2022, 27 (24)

[36] Metal-organic framework (MOF)-derived amorphous nickel boride: an electroactive material for electrochemical energy conversion and storage application [J].

Tripathy, Rajat K. ;

Samantara, Aneeya K. ;

Behera, J. N. .

SUSTAINABLE ENERGY & FUELS, 2021, 5 (04) :1184-1193

[37] Self-assembled materials for electrochemical energy storage [J].

Chen, Hao ;

Benedek, Peter ;

Fisher, Khande-Jae ;

Wood, Vanessa ;

Cui, Yi .

MRS BULLETIN, 2020, 45 (10) :815-822

[38] Trimetallic metal-organic frameworks and derived materials for environmental remediation and electrochemical energy storage and conversion [J].

Luo, Xinzhi ;

Abazari, Reza ;

Tahir, Muhammad ;

Fan, Wei Keen ;

Kumar, Anuj ;

Kalhorizadeh, Tina ;

Kirillov, Alexander M. ;

Amani-Ghadim, Ali Reza ;

Chen, Jing ;

Zhou, Yingtang .

COORDINATION CHEMISTRY REVIEWS, 2022, 461

[39] Ion transport behaviors in MXenes for electrochemical energy storage and conversion [J].

Fei, Ling ;

Lei, Lei ;

Xu, Hui ;

Guo, Xinghua ;

Chen, Bo ;

Han, Xu ;

Chen, Xun ;

Huang, Qing ;

Wang, Degao .

CARBON ENERGY, 2025, 7 (03)

[40] Immobilization of metal active centers in reticular framework materials for photocatalytic energy conversion [J].

Wang, Shuo ;

Guo, Wei ;

Li, Chao ;

Weng, Bo ;

Liu, Shuai ;

Han, Ning ;

Long, Jinlin ;

Zhang, Honglei .

JOURNAL OF MATERIALS CHEMISTRY A, 2024, 12 (22) :12907-12925

← 1 2 3 4 5 →