The supramolecular chemistry of monodisperse 1,3,5-triazine oligomers

被引:0
作者
Escobar, Luis [1 ,2 ]
Hunter, Christopher A. [1 ]
机构
[1] Univ Cambridge, Yusuf Hamied Dept Chem, Lensfield Rd, Cambridge CB2 1EW, England
[2] Barcelona Inst Sci & Technol BIST, Inst Chem Res Catalonia ICIQ, Ave Paisos Catalans 16, Tarragona 43007, Spain
基金
欧洲研究理事会; 欧盟地平线“2020”;
关键词
IN-VIVO TOXICITY; TRIAZINE DENDRIMERS; ANION-PI; CYANURIC ACID; BUILDING-BLOCKS; MOLECULAR RECOGNITION; CONVERGENT SYNTHESES; DUPLEX OLIGOMERS; DIVERGENT ROUTE; BONDING MOTIFS;
D O I
10.1039/d5ob00321k
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Organic compounds based on 1,3,5-triazine scaffolds are utilised in practical applications in agriculture, as well as in the pharmaceutical and plastic industries. In fundamental research, 1,3,5-triazines are used as building blocks for the construction of oligomers that are relevant to the areas of supramolecular chemistry, chemical biology and polymer science. Here, we review the molecular recognition and self-assembly properties of monodisperse linear and branched oligomers, macrocycles, and dendrimers of 1,3,5-triazine. We focus mainly on experimental studies conducted in solution, describing the key interactions and structural features of these systems.
引用
收藏
页码:3520 / 3534
页数:15
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